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A solution contains three cations, Ba$^{2+}$, Cu$^{2+}$ and Pb$^{2+}$ - HSC - SSCE Chemistry - Question 22 - 2013 - Paper 1

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Question 22

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A solution contains three cations, Ba$^{2+}$, Cu$^{2+}$ and Pb$^{2+}$. The flow chart indicates the plan used to confirm the identity of these cations. Solution con... show full transcript

Worked Solution & Example Answer:A solution contains three cations, Ba$^{2+}$, Cu$^{2+}$ and Pb$^{2+}$ - HSC - SSCE Chemistry - Question 22 - 2013 - Paper 1

Step 1

Name Precipitate 2.

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Answer

Precipitate 2 is Barium Sulfate (BaSO4_4).

Step 2

Write a balanced net ionic equation for the formation of Precipitate 1.

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Answer

The balanced net ionic equation for the formation of Precipitate 1, which is Lead(II) Chloride (PbCl2_2), is:

Pb2+(aq)+2Cl(aq)PbCl2(s)Pb^{2+} (aq) + 2Cl^{-} (aq) \rightarrow PbCl_{2} (s)

Step 3

Suggest a test and the expected result that would confirm the identity of the metal cation remaining in Filtrate 2.

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Answer

A suitable test for confirming the identity of the metal cation in Filtrate 2 is to add a few drops of sodium hydroxide (NaOH) solution, which will cause the formation of a blue precipitate if Copper(II) ions (Cu2+^{2+}) are present.

Expected Result: A blue precipitate indicates the presence of Copper(II) ions.

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