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Four students were asked to test a solution for the presence of a cation by using various anions - HSC - SSCE Chemistry - Question 15 - 2001 - Paper 1

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Four students were asked to test a solution for the presence of a cation by using various anions. The students obtained these results: Student Chloride Sulfate C... show full transcript

Worked Solution & Example Answer:Four students were asked to test a solution for the presence of a cation by using various anions - HSC - SSCE Chemistry - Question 15 - 2001 - Paper 1

Step 1

Which student had results consistent with this conclusion?

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Answer

To determine which student had results consistent with the conclusion that Pb<sup>2+</sup> is present, we must analyze the precipitate results for each anion:

  1. Chloride: Lead(II) chloride (PbCl<sub>2</sub>) is soluble in water, so a precipitate indicates the absence of Pb<sup>2+</sup>.
  2. Sulfate: Lead(II) sulfate (PbSO<sub>4</sub>) is an insoluble salt, so a precipitate confirms the presence of Pb<sup>2+</sup>.
  3. Carbonate: Lead(II) carbonate (PbCO<sub>3</sub>) is also insoluble, so a precipitate also confirms the presence of Pb<sup>2+</sup>.

Now let's evaluate each student's results:

  • Student A: No precipitate for chloride, no precipitate for sulfate, precipitate for carbonate (inconsistent)
  • Student B: Precipitate for chloride, no precipitate for sulfate, no precipitate for carbonate (inconsistent)
  • Student C: Precipitate for chloride, precipitate for sulfate, precipitate for carbonate (consistent)
  • Student D: No precipitate for chloride, precipitate for sulfate, no precipitate for carbonate (inconsistent)

Based on this analysis, Student C had results that are consistent with the conclusion that Pb<sup>2+</sup> is present.

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