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The flow chart shows a series of steps involved in the production of ethyl butanoate - HSC - SSCE Chemistry - Question 20 - 2005 - Paper 1

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The flow chart shows a series of steps involved in the production of ethyl butanoate. Describe the chemistry and procedure involved in each of these steps, using di... show full transcript

Worked Solution & Example Answer:The flow chart shows a series of steps involved in the production of ethyl butanoate - HSC - SSCE Chemistry - Question 20 - 2005 - Paper 1

Step 1

Glucose to Mixture containing Ethanol

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The initial step involves the fermentation of glucose to produce a mixture containing ethanol and carbon dioxide. The chemical equation for this process is:

ightarrow 2C_2H_5OH + 2CO_2$$ This typically occurs in the presence of yeast under anaerobic conditions at a temperature of about 30°C. The yeast ferments the glucose, converting it into ethanol and carbon dioxide.

Step 2

Mixture containing Ethanol to Pure Ethanol

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The next step is the distillation of the mixture to separate pure ethanol from the fermentation products. This is done by heating the mixture, as ethanol has a lower boiling point (78.37°C) compared to water (100°C). During distillation, the ethanol vaporizes and can be collected in a separate container, resulting in pure ethanol.

Step 3

Pure Ethanol to Ethyl Butanoate

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The final step is the esterification of ethanol to form ethyl butanoate. This reaction involves ethanol reacting with butanoic acid in the presence of a catalyst, typically concentrated sulfuric acid. The chemical equation is:

C2H5OH+C4H8O2C6H12O2+H2OC_2H_5OH + C_4H_8O_2 \rightarrow C_6H_{12}O_2 + H_2O

This reaction is conducted under reflux conditions to ensure that it proceeds to completion. The product can be purified through simple distillation or extraction.

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