A sequence of chemical reactions, starting with 2-methylprop-1-ene, is shown in the flow chart - HSC - SSCE Chemistry - Question 26 - 2021 - Paper 1
Question 26
A sequence of chemical reactions, starting with 2-methylprop-1-ene, is shown in the flow chart.
(a) Complete the flow chart by drawing structural formulae for compo... show full transcript
Worked Solution & Example Answer:A sequence of chemical reactions, starting with 2-methylprop-1-ene, is shown in the flow chart - HSC - SSCE Chemistry - Question 26 - 2021 - Paper 1
Step 1
Complete the flow chart by drawing structural formula for compound A
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Answer
Compound A is produced from the hydration of 2-methylprop-1-ene with dilute H2SO4, leading to 2-methylpropan-2-ol:
HO
|
H3C-C-CH3
|
H
Step 2
Complete the flow chart by drawing structural formula for compound B
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Answer
Compound B results from the oxidation of compound A (2-methylpropan-2-ol) with acidified KMnO4, forming 2-methylpropan-2-one:
O
||
H3C-C-CH3
|
H
Step 3
Complete the flow chart by drawing structural formula for compound C
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Answer
Compound C is formed through a substitution reaction of compound B with concentrated HCl and ZnCl2, resulting in 2-chloro-2-methylpropane:
Cl
|
H3C-C-CH3
|
H
Step 4
Complete the flow chart by drawing structural formula for compound D
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Answer
Compound D is produced by refluxing compound C with methanol and concentrated H2SO4, yielding methyl 2-methylpropanoate:
O
||
H3C-C-CH3
|
OCH3
Step 5
Provide TWO reasons for using this technique.
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Answer
Reflux retains the volatile reactants and products, preventing loss of materials during the reaction.
It allows the reaction to proceed at a higher temperature without boiling off the solvents or reactants.