Students conducted an experiment to determine ΔH for the reaction between sodium hydroxide and hydrochloric acid - HSC - SSCE Chemistry - Question 26 - 2022 - Paper 1
Question 26
Students conducted an experiment to determine ΔH for the reaction between sodium hydroxide and hydrochloric acid.
The data from one student are shown in the table b... show full transcript
Worked Solution & Example Answer:Students conducted an experiment to determine ΔH for the reaction between sodium hydroxide and hydrochloric acid - HSC - SSCE Chemistry - Question 26 - 2022 - Paper 1
Step 1
Calculate the heat energy released in this experiment.
96%
114 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
To calculate the heat energy released, we need to find the change in temperature (
ΔT) and the mass of the solution.
Calculate ΔT:
Average initial temperature of the solutions:
Tavg=221.0+21.2=21.1°C
Change in temperature:
ΔT=24.4°C−21.1°C=3.3K
Calculate mass of the final solution:
Mass of HCl solution = 100.7 g
Mass of NaOH solution = 102.0 g
Total mass of solution = 100.7 g + 102.0 g = 202.7 g = 0.2027 kg
Use the specific heat capacity of water:
Specific heat capacity of water = 4.18 x 10³ J K⁻¹ kg⁻¹
Calculate heat energy (q):
Using the formula:
q=mcΔT where m is mass, c is specific heat capacity, and ΔT is temperature change.
q=0.2027kgimes4.18×103JK−1kg−1×3.3K=2796J=2.8kJ
Step 2
Use this value to determine the enthalpy of neutralisation, ΔH, in kJ mol⁻¹, for the reaction shown.
99%
104 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
To find the enthalpy of neutralisation, we first determine the amount of HCl that reacted.