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Students conducted an experiment to determine ΔH for the reaction between sodium hydroxide and hydrochloric acid - HSC - SSCE Chemistry - Question 26 - 2022 - Paper 1

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Students conducted an experiment to determine ΔH for the reaction between sodium hydroxide and hydrochloric acid. The data from one student are shown in the table b... show full transcript

Worked Solution & Example Answer:Students conducted an experiment to determine ΔH for the reaction between sodium hydroxide and hydrochloric acid - HSC - SSCE Chemistry - Question 26 - 2022 - Paper 1

Step 1

Calculate the heat energy released in this experiment.

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Answer

To calculate the heat energy released, we need to find the change in temperature ( ΔT) and the mass of the solution.

  1. Calculate ΔT:

    • Average initial temperature of the solutions:

      Tavg=21.0+21.22=21.1°CT_{avg} = \frac{21.0 + 21.2}{2} = 21.1 °C

    • Change in temperature:

      ΔT=24.4°C21.1°C=3.3KΔT = 24.4 °C - 21.1 °C = 3.3 K

  2. Calculate mass of the final solution:

    • Mass of HCl solution = 100.7 g
    • Mass of NaOH solution = 102.0 g
    • Total mass of solution = 100.7 g + 102.0 g = 202.7 g = 0.2027 kg
  3. Use the specific heat capacity of water:

    • Specific heat capacity of water = 4.18 x 10³ J K⁻¹ kg⁻¹
  4. Calculate heat energy (q):

    • Using the formula:

      q=mcΔTq = mcΔT where m is mass, c is specific heat capacity, and ΔT is temperature change.

    q=0.2027kgimes4.18×103JK1kg1×3.3K=2796J=2.8kJq = 0.2027 kg imes 4.18 \times 10^3 J K^{-1} kg^{-1} \times 3.3 K = 2796 J = 2.8 kJ

Step 2

Use this value to determine the enthalpy of neutralisation, ΔH, in kJ mol⁻¹, for the reaction shown.

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Answer

To find the enthalpy of neutralisation, we first determine the amount of HCl that reacted.

  1. Moles of HCl reacted:

    • Volume of HCl solution = 0.100 L
    • Concentration of HCl = 0.50 mol L⁻¹

    mol  of  HCl=0.100L×0.50molL=0.050molmol \; of \; HCl = 0.100 L \times 0.50 \frac{mol}{L} = 0.050 mol

  2. Calculate ΔH using the heat energy:

    • Given heat energy (q) = 2.6 x 10³ J = 2.6 kJ

    • Enthalpy change:

      ΔH=qmol  of  HCl=2.6kJ0.050mol=52kJmol1ΔH = \frac{q}{mol \; of \; HCl} = \frac{2.6 kJ}{0.050 mol} = -52 kJ mol^{-1}

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