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Sodium reacts with water to give hydrogen gas and sodium hydroxide solution - HSC - SSCE Chemistry - Question 14 - 2013 - Paper 1

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Sodium reacts with water to give hydrogen gas and sodium hydroxide solution. What volume of gas would be produced from the reaction of 22.99 g of sodium at 25°C and... show full transcript

Worked Solution & Example Answer:Sodium reacts with water to give hydrogen gas and sodium hydroxide solution - HSC - SSCE Chemistry - Question 14 - 2013 - Paper 1

Step 1

Calculate the number of moles of sodium

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Answer

To find the number of moles of sodium, we use the formula:

n=mMn = \frac{m}{M}

where:

  • nn is the number of moles
  • mm is the mass of sodium (22.99 g)
  • MM is the molar mass of sodium (approximately 23 g/mol)

Calculating: n=22.99231.00moln = \frac{22.99}{23} \approx 1.00 \, \text{mol}

Step 2

Identify the reaction producing hydrogen gas

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Answer

The reaction of sodium with water is given by:

2Na+2H2O2NaOH+H22 \text{Na} + 2 \text{H}_2\text{O} \rightarrow 2 \text{NaOH} + \text{H}_2

From this reaction, 2 moles of sodium produce 1 mole of hydrogen gas. Thus, 1 mole of sodium will produce:

1.002=0.50mol of H2\frac{1.00}{2} = 0.50 \, \text{mol of } H_2

Step 3

Calculate the volume of hydrogen gas at the given conditions

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Answer

To calculate the volume of hydrogen gas produced, we can use the ideal gas law:

PV=nRTPV = nRT

Rearranging gives:

V=nRTPV = \frac{nRT}{P}

Where:

  • R=8.31J/(mol K)R = 8.31 \, \text{J/(mol K)}
  • Convert pressure PP from kPa to Pa: 100kPa=100,000Pa100 \, \text{kPa} = 100,000 \, \text{Pa}
  • Convert temperature to Kelvin: 25°C=298K25°C = 298 \, K

Inserting the values: V=0.50mol×8.31J/(mol K)×298K100,000extPaV = \frac{0.50 \, \text{mol} \times 8.31 \, \text{J/(mol K)} \times 298 \, K}{100,000 \, ext{Pa}}

Calculating: V0.01240m3V \approx 0.01240 \, m^3

Converting cubic meters to liters (1 m³ = 1000 L): V12.40LV \approx 12.40 \, L

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