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A low molecular weight biopolymer is being investigated for its suitability for medical use - HSC - SSCE Chemistry - Question 18 - 2022 - Paper 1

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A low molecular weight biopolymer is being investigated for its suitability for medical use. In one trial a molecular weight of 2900 ± 100 g mol⁻¹ proved to be optim... show full transcript

Worked Solution & Example Answer:A low molecular weight biopolymer is being investigated for its suitability for medical use - HSC - SSCE Chemistry - Question 18 - 2022 - Paper 1

Step 1

Which will produce the suitable biopolymer?

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Answer

To determine which option produces a suitable biopolymer, we need to calculate the molecular weight based on the number of units provided. The target molecular weight is 2900 g mol⁻¹ with a tolerance of ± 100 g mol⁻¹.

Calculating the Molecular Weight:

  1. Option A:

    • Molar mass = 88.01 g mol⁻¹
    • Number of units = 42
    • Total molecular weight = 88.01imes42=3694.42extgmol188.01 imes 42 = 3694.42 ext{ g mol}^{-1}
    • This exceeds the optimum weight.
  2. Option B:

    • Molar mass = 88.01 g mol⁻¹
    • Number of units = 33
    • Total molecular weight = 88.01imes33=2904.33extgmol188.01 imes 33 = 2904.33 ext{ g mol}^{-1}
    • This also exceeds the optimum weight.
  3. Option C:

    • Molar mass = 90.078 g mol⁻¹
    • Number of units = 32
    • Total molecular weight = 90.078imes32=2882.49extgmol190.078 imes 32 = 2882.49 ext{ g mol}^{-1}
    • This value is acceptable as it is within the range (2900 ± 100).
  4. Option D:

    • Molar mass = 90.078 g mol⁻¹
    • Number of units = 40
    • Total molecular weight = 90.078imes40=3603.12extgmol190.078 imes 40 = 3603.12 ext{ g mol}^{-1}
    • This exceeds the optimum weight.

Conclusion:

The suitable biopolymer that meets the molecular weight criteria of 2900 ± 100 g mol⁻¹ is Option C, as it has a total molecular weight of 2882.49 g mol⁻¹.

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