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The figure shows the pH values of some substances - HSC - SSCE Chemistry - Question 7 - 2004 - Paper 1

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The figure shows the pH values of some substances. Based on the pH values shown in the figure, which of the following statements about the concentration of hydrogen... show full transcript

Worked Solution & Example Answer:The figure shows the pH values of some substances - HSC - SSCE Chemistry - Question 7 - 2004 - Paper 1

Step 1

It is twice as great in milk as that in lemon juice.

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Answer

This statement can be evaluated by understanding that the pH of lemon juice is typically around 2, while milk has a pH of about 6. The concentration of hydrogen ions ext[H+] ext{[H}^+\text{]} can be calculated using the formula:

ext[H+]=10pH ext{[H}^+\text{]} = 10^{-\text{pH}}

For lemon juice:

ext[H+]lemon=102=0.01M ext{[H}^+\text{]}_{lemon} = 10^{-2} = 0.01\,M

For milk:

ext[H+]milk=106=0.000001M ext{[H}^+\text{]}_{milk} = 10^{-6} = 0.000001\,M

Thus, this statement is incorrect.

Step 2

It is 1 000 000 times greater in soap than in wine.

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Answer

To analyze this, we compare the pH values of soap (around 12) and wine (around 3). Using the same formula:

For soap:

ext[H+]soap=1012=1.0×1012M ext{[H}^+\text{]}_{soap} = 10^{-12} = 1.0\times 10^{-12}\,M

For wine:

ext[H+]wine=103=0.001M ext{[H}^+\text{]}_{wine} = 10^{-3} = 0.001\,M

Thus, the ratio:

ext[H+]soapext[H+]wine=1012103=1012+3=109\frac{ ext{[H}^+\text{]}_{soap}}{ ext{[H}^+\text{]}_{wine}} = \frac{10^{-12}}{10^{-3}} = 10^{-12 + 3} = 10^{-9}

This is not equal to 1,000,000. Therefore, this statement is incorrect.

Step 3

It is three times greater in wine than in bleach solution.

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Answer

The pH of bleach is typically around 12.5:

For bleach:

ext[H+]bleach=1012.53.16×1013M ext{[H}^+\text{]}_{bleach} = 10^{-12.5} \approx 3.16 \times 10^{-13}\,M

Thus, the ratio of concentration:

ext[H+]wineext[H+]bleach=0.0013.16×10133160\frac{ ext{[H}^+\text{]}_{wine}}{ ext{[H}^+\text{]}_{bleach}} = \frac{0.001}{3.16 \times 10^{-13}} \approx 3160

This shows that wine is not three times greater than bleach. Therefore, this statement is incorrect.

Step 4

It is 1 000 times greater in distilled water than in soap.

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Answer

The pH of distilled water is about 7:

For distilled water:

ext[H+]water=107M ext{[H}^+\text{]}_{water} = 10^{-7}\,M

Previously calculated for soap:

[H+]soap=1012M\text{[H}^+\text{]}_{soap} = 10^{-12}\,M

Thus, the ratio:

ext[H+]waterext[H+]soap=1071012=105=100000\frac{ ext{[H}^+\text{]}_{water}}{ ext{[H}^+\text{]}_{soap}} = \frac{10^{-7}}{10^{-12}} = 10^{5} = 100000

This shows distilled water is indeed much greater in hydrogen ion concentration than soap, making this statement correct.

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