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10^{-2} mole of HCl is added to exactly 1.00 L of pure water at 25°C - VCE - SSCE Chemistry - Question 5 - 2004 - Paper 1

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10^{-2} mole of HCl is added to exactly 1.00 L of pure water at 25°C. The change in pH of the water is closest to A. 10^{-2} B. 2 C. 5 D. 7

Worked Solution & Example Answer:10^{-2} mole of HCl is added to exactly 1.00 L of pure water at 25°C - VCE - SSCE Chemistry - Question 5 - 2004 - Paper 1

Step 1

Calculate the concentration of HCl in the solution

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Answer

To determine the change in pH, first calculate the concentration of HCl after adding 10^{-2} moles to 1.00 L of water.

The concentration, [ C = \frac{n}{V} = \frac{10^{-2} \text{ moles}}{1.00 \text{ L}} = 10^{-2} \text{ M} ]

Step 2

Determine the pH of the solution

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Answer

Hydrochloric acid (HCl) is a strong acid, which means it fully dissociates in solution. Thus, the concentration of hydrogen ions, [ [H^+] ], is equal to the concentration of HCl:

[ [H^+] = 10^{-2} \text{ M} ]

Now, compute the pH:

[ pH = -\log[H^+] = -\log(10^{-2}) = 2 ]

Step 3

Determine the change in pH

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Answer

Since the initial pH of pure water at 25°C is 7, the change in pH can be calculated as follows:

[ \Delta pH = pH_{ ext{final}} - pH_{ ext{initial}} = 2 - 7 = -5 ]

The absolute value of the change is 5, so the closest answer choice reflecting the change in pH is 2 (since it indicates a shift towards acidity).

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