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A solution of sodium hydroxide (NaOH) has a pH of 10 - VCE - SSCE Chemistry - Question 12 - 2005 - Paper 1

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A solution of sodium hydroxide (NaOH) has a pH of 10. 10 mL of this solution is mixed with 990 mL of water. The pH of the diluted solution is closest to A. 8 B. 9 C.... show full transcript

Worked Solution & Example Answer:A solution of sodium hydroxide (NaOH) has a pH of 10 - VCE - SSCE Chemistry - Question 12 - 2005 - Paper 1

Step 1

Calculate the initial concentration of NaOH

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Answer

First, we know that pH is related to the concentration of hydroxide ions. The relationship can be established as follows:

a = 10^{-(14 - 10)} = 10^{-4} ext{ mol/L}

This concentration signifies the initial molarity of the NaOH solution.

Step 2

Determine the moles of NaOH in 10 mL

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Answer

The volume of the solution is 10 mL, which is equivalent to 0.01 L. Thus, the moles of NaOH can be calculated as follows:

[ \text{Moles of NaOH} = \text{concentration} \times \text{volume} = 10^{-4} \text{ mol/L} \times 0.01 \text{ L} = 10^{-6} \text{ mol} ]

Step 3

Calculate the final volume of the solution

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Answer

The total volume after mixing 10 mL of NaOH with 990 mL of water is:

[ \text{Total Volume} = 10 \text{ mL} + 990 \text{ mL} = 1000 \text{ mL} = 1.0 ext{ L} ]

Step 4

Calculate the new concentration of NaOH in the diluted solution

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Answer

The new concentration can be calculated using the moles and the final volume:

[ \text{Concentration of NaOH} = \frac{10^{-6} \text{ mol}}{1.0 ext{ L}} = 10^{-6} ext{ mol/L} ]

Step 5

Determine the pOH and then the pH of the diluted solution

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Answer

Knowing that pOH is calculated as follows:

[ \text{pOH} = -\log[OH^-] = -\log(10^{-6}) = 6 ]

We can find the pH using the relation:

[ \text{pH} + \text{pOH} = 14 ]

Thus,

[ \text{pH} = 14 - 6 = 8 ]

The pH of the diluted solution is closest to 8.

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