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In a gas-fired power station, the energy available from the above reaction is used to convert water in a boiler from liquid water to steam, H₂O(l) → H₂O(g) ΔH = +44.0 kJ mol⁻¹ The maximum mass of water, in grams, that could be converted from liquid water to steam by the complete oxidation of one mole of methane is A - VCE - SSCE Chemistry - Question 4 - 2004 - Paper 1

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In-a-gas-fired-power-station,-the-energy-available-from-the-above-reaction-is-used-to-convert-water-in-a-boiler-from-liquid-water-to-steam,--H₂O(l)-→-H₂O(g)---ΔH-=-+44.0-kJ-mol⁻¹--The-maximum-mass-of-water,-in-grams,-that-could-be-converted-from-liquid-water-to-steam-by-the-complete-oxidation-of-one-mole-of-methane-is--A-VCE-SSCE Chemistry-Question 4-2004-Paper 1.png

In a gas-fired power station, the energy available from the above reaction is used to convert water in a boiler from liquid water to steam, H₂O(l) → H₂O(g) ΔH = +... show full transcript

Worked Solution & Example Answer:In a gas-fired power station, the energy available from the above reaction is used to convert water in a boiler from liquid water to steam, H₂O(l) → H₂O(g) ΔH = +44.0 kJ mol⁻¹ The maximum mass of water, in grams, that could be converted from liquid water to steam by the complete oxidation of one mole of methane is A - VCE - SSCE Chemistry - Question 4 - 2004 - Paper 1

Step 1

The maximum mass of water, in grams, that could be converted from liquid water to steam by the complete oxidation of one mole of methane is

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Answer

To solve this problem, we need to determine how much heat is produced by the complete oxidation of one mole of methane (CH₄) and then use that to find out how much water can be converted to steam.

  1. Determine the Heat Released by Methane: The balanced chemical equation for the complete combustion of methane is:

    CH4(g)+2O2(g)CO2(g)+2H2O(g)CH₄(g) + 2O₂(g) → CO₂(g) + 2H₂O(g)

    The combustion of one mole of methane releases approximately 890 kJ of energy.

  2. Calculate the Energy Needed to Convert Water to Steam: The enthalpy change for converting liquid water to steam at 100°C is given as +44.0 kJ/mol. This is the amount of energy required to convert one mole of water to steam.

  3. Calculate How Many Moles of Water Can Be Vaporized: Now we calculate how many moles of water can be vaporized using the total energy from the combustion of methane:

    Let the number of moles of water vaporized be n:

    n \\ = 20.22727 ext{ mol}$$
  4. Convert Moles of Water to Grams: To find the mass in grams, multiply the number of moles by the molar mass of water:

    Molar mass of H₂O = 18 g/mol.

    Mass=nimesextMolarmass=20.22727extmolimes18extg/mol=364.0909extgMass = n imes ext{Molar mass} = 20.22727 ext{ mol} imes 18 ext{ g/mol} = 364.0909 ext{ g}

  5. Choose the Closest Answer: Rounding down to match the provided options, we see that 368 g is the maximum mass of water that can be vaporized, which corresponds to option D.

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