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What mass of butane (M = 58.0 g mol⁻¹) must undergo complete combustion to raise the temperature of 100.0 g of water by 1.00 °C? Assume that there is no heat loss. - VCE - SSCE Chemistry - Question 8 - 2011 - Paper 1

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Question 8

What-mass-of-butane-(M-=-58.0-g-mol⁻¹)-must-undergo-complete-combustion-to-raise-the-temperature-of-100.0-g-of-water-by-1.00-°C?-Assume-that-there-is-no-heat-loss.-VCE-SSCE Chemistry-Question 8-2011-Paper 1.png

What mass of butane (M = 58.0 g mol⁻¹) must undergo complete combustion to raise the temperature of 100.0 g of water by 1.00 °C? Assume that there is no heat loss.

Worked Solution & Example Answer:What mass of butane (M = 58.0 g mol⁻¹) must undergo complete combustion to raise the temperature of 100.0 g of water by 1.00 °C? Assume that there is no heat loss. - VCE - SSCE Chemistry - Question 8 - 2011 - Paper 1

Step 1

Calculate the amount of heat needed to raise the temperature of the water.

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Answer

The heat required (q) to raise the temperature of the water can be calculated using the formula:

q=mimescimesriangleTq = m imes c imes riangle T

where:

  • mm is the mass of water (100.0 g)
  • cc is the specific heat capacity of water (4.18 J g⁻¹ °C⁻¹)
  • T\triangle T is the change in temperature (1.00 °C)

Substituting the values:

q=100.0extgimes4.18extJg1°C1imes1.00ext°C=418extJq = 100.0 ext{ g} imes 4.18 ext{ J g⁻¹ °C⁻¹} imes 1.00 ext{ °C} = 418 ext{ J}

Step 2

Determine the heat released per mole of butane combusted.

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Answer

The standard heat of combustion for butane is approximately -2877 kJ/mol. Converting this value to joules:

-2877 kJ/mol = -2877000 J/mol.

Therefore, the heat released by combusting one mole of butane is 2877000 J.

Step 3

Calculate the number of moles of butane required to release the necessary heat.

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Answer

To find the moles of butane (n) needed to generate 418 J, use the formula:

n=qΔHcombustionn = \frac{q}{\Delta H_{combustion}}

Substituting the values:

n=418extJ2877000extJ/mol0.000145extmoln = \frac{418 ext{ J}}{2877000 ext{ J/mol}} \approx 0.000145 ext{ mol}

Step 4

Calculate the mass of butane required using its molar mass.

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Answer

Using the molar mass of butane (M = 58.0 g/mol), the mass of butane (m) can be calculated as:

m=n×Mm = n \times M

Substituting the values:

m=0.000145extmol×58.0extg/mol0.00841extgm = 0.000145 ext{ mol} \times 58.0 ext{ g/mol} \approx 0.00841 ext{ g}

This is approximately 8.44 g, making the correct answer:

D. 8.44 x 10³ g

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