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When molecular iodine, I₂, reacts with an unsaturated compound, one molecule of iodine adds across each double bond - VCE - SSCE Chemistry - Question 19 - 2008 - Paper 1

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Question 19

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When molecular iodine, I₂, reacts with an unsaturated compound, one molecule of iodine adds across each double bond. Unsaturated fatty acids react in this way with i... show full transcript

Worked Solution & Example Answer:When molecular iodine, I₂, reacts with an unsaturated compound, one molecule of iodine adds across each double bond - VCE - SSCE Chemistry - Question 19 - 2008 - Paper 1

Step 1

Identify the relationship between moles of iodine and double bonds

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Answer

Since one molecule of iodine (I₂) adds across each double bond, the number of moles of I₂ used can help determine the number of double bonds present in the fatty acid under consideration.

Step 2

Calculate number of double bonds in the fatty acid

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Answer

Given that 0.150 mol of fatty acid reacts with 0.300 mol of iodine, we can derive the number of double bonds. Since each double bond consumes one molecule of iodine, the number of double bonds is given by the equation:

[ \text{Number of double bonds} = \frac{0.300 \text{ mol I₂}}{1} = 0.300 \text{ double bonds} ]

This indicates that the fatty acid has 2 double bonds.

Step 3

Determine which fatty acid has 2 double bonds

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Answer

Among the options:

  • Lauric acid has 0 double bonds.
  • Linoleic acid has 2 double bonds.
  • Palmitoleic acid has 1 double bond.
  • Arachidonic acid has 4 double bonds.

Thus, the fatty acid that could be is linoleic acid (B).

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