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A chemical reaction has a ΔH of –150 kJ mol⁻¹ and the activation energy for its reverse reaction is 350 kJ mol⁻¹ - VCE - SSCE Chemistry - Question 8 - 2007 - Paper 1

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A chemical reaction has a ΔH of –150 kJ mol⁻¹ and the activation energy for its reverse reaction is 350 kJ mol⁻¹. The activation energy, in kJ mol⁻¹, of the forward ... show full transcript

Worked Solution & Example Answer:A chemical reaction has a ΔH of –150 kJ mol⁻¹ and the activation energy for its reverse reaction is 350 kJ mol⁻¹ - VCE - SSCE Chemistry - Question 8 - 2007 - Paper 1

Step 1

Calculate the Activation Energy for the Forward Reaction

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Answer

To find the activation energy of the forward reaction, we can use the relationship between the activation energies of the forward and reverse reactions:

Eaforward=Eareverse+extΔHE_a^{forward} = E_a^{reverse} + ext{Δ}H

Substituting the given values:

  • Activation energy of the reverse reaction, Eareverse=350extkJmol1E_a^{reverse} = 350 ext{ kJ mol}^{-1}
  • Enthalpy change, ΔH=150extkJmol1ΔH = -150 ext{ kJ mol}^{-1}

Thus,

Eaforward=350extkJmol1150extkJmol1E_a^{forward} = 350 ext{ kJ mol}^{-1} - 150 ext{ kJ mol}^{-1}

Calculating this gives:

Eaforward=350150=200extkJmol1E_a^{forward} = 350 - 150 = 200 ext{ kJ mol}^{-1}

Therefore, the activation energy of the forward reaction is +200 kJ mol⁻¹.

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