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Esters are the basis of many naturally occurring odours and are therefore widely used in the creation of artificial flavours - VCE - SSCE Chemistry - Question 3 - 2003 - Paper 1

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Esters are the basis of many naturally occurring odours and are therefore widely used in the creation of artificial flavours. Methyl butanoate is a component of the ... show full transcript

Worked Solution & Example Answer:Esters are the basis of many naturally occurring odours and are therefore widely used in the creation of artificial flavours - VCE - SSCE Chemistry - Question 3 - 2003 - Paper 1

Step 1

a. Give a simple structure for the ester methyl butanoate.

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Answer

The structure for the ester methyl butanoate is given below:

    O
    ||
CH₃-CH₂-CH₂-COO-CH₃

This structure indicates that methyl butanoate consists of a butanoate group and a methyl group attached through an ester bond.

Step 2

b. Using 1-butanol and methanol as starting materials give chemical equations showing the steps in the preparation of methyl butanoate. Give the name of any catalyst used.

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Answer

  1. Conversion of 1-butanol to butanoic acid:
  CH₃-CH₂-CH₂-CH₂OH  →  CH₃-CH₂-CH₂-COOH
  (1-butanol)         (butanoic acid)
  1. Reaction of butanoic acid with methanol to produce the ester:
  CH₃-CH₂-CH₂-COOH + CH₃OH  ⇌  CH₃-CH₂-CH₂-COO-CH₃ + H₂O
  (butanoic acid)         (methanol)    (methyl butanoate)

In this step, sulfuric acid (H₂SO₄) is used as a catalyst to facilitate the esterification process.

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