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a. A structure for the disaccharide maltose (C12H22O11) is given below - VCE - SSCE Chemistry - Question 4 - 2007 - Paper 1

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a. A structure for the disaccharide maltose (C12H22O11) is given below. i. Maltose undergoes enzyme-catalysed hydrolysis during digestion. Give the molecular formu... show full transcript

Worked Solution & Example Answer:a. A structure for the disaccharide maltose (C12H22O11) is given below - VCE - SSCE Chemistry - Question 4 - 2007 - Paper 1

Step 1

i. Maltose undergoes enzyme-catalysed hydrolysis during digestion. Give the molecular formula of the product of this hydrolysis.

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Answer

The hydrolysis of maltose yields two molecules of glucose. The molecular formula of glucose is C6H12O6. Therefore, the molecular formula for the product of hydrolysis is C12H22O12 (2 × C6H12O6).

Step 2

ii. Write a balanced equation for the combustion of one mole of maltose (C12H22O11) in the presence of excess oxygen.

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Answer

The balanced equation for the combustion of maltose can be represented as follows:

C12H22O11+12O212CO2+11H2OC_{12}H_{22}O_{11} + 12 O_{2} \rightarrow 12 CO_{2} + 11 H_{2}O

Step 3

iii. The monosaccharide from the hydrolysis of maltose also undergoes combustion in excess oxygen. Combustion of one mole of maltose also releases 2816 kJ. Given the value of ΔH for the combustion of one mole of maltose and explain the reasoning behind your estimate.

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Answer

The ΔH value for the combustion of one mole of maltose can be estimated around -5632 kJ. This is calculated by recognizing that the combustion of glucose (a product of maltose hydrolysis) typically releases about 2816 kJ per mole. Since hydrolysis yields two glucose molecules, the value is doubled, leading to the approximation of -5632 kJ, considering complete combustion of all glucose products.

Step 4

ii. In the space below, clearly draw a structural formula for glycerol. Show all bonds.

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Answer

The structural formula for glycerol (C3H8O3) is drawn as:

   H   H   H
   |   |   |
H—C—C—C—OH
   |   |   |
   OH  OH  H

This representation shows all bonds including the hydroxyl (OH) groups.

Step 5

i. Write a balanced equation for the formation of methyl stearate from methanol and stearic acid.

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Answer

The balanced equation for the formation of methyl stearate from methanol and stearic acid can be represented as:

C18H36O2+CH3OHC18H36O2+H2OC_{18}H_{36}O_{2} + CH_{3}OH \rightarrow C_{18}H_{36}O_{2}^{*} + H_{2}O

Here, C18H36O2* represents methyl stearate.

Step 6

ii. On the product formed in part i, clearly circle a complete ester group.

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Answer

In the structure of methyl stearate, the ester functional group can be identified as:

   O
   ||
H—C—C—C—C—...—O—CH3 

In this structure, the bond between the carbonyl (C=O) and the oxygen (–O–) adjacent to the methyl group (–O–CH3) is the complete ester group.

Step 7

In terms of its structure, explain why the lecithin molecule is able to act as an emulsifier.

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Answer

Lecithin is a phospholipid containing both hydrophilic (water-attracting) and hydrophobic (water-repelling) regions. Its structure includes a hydrophilic phosphate head and two hydrophobic fatty acid tails. This unique amphiphilic nature allows lecithin to interact with both water and oil, stabilizing emulsions by reducing surface tension and preventing separation.

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