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The amount of iron in a newly developed, heat-resistant aluminium alloy is to be determined - VCE - SSCE Chemistry - Question 1 - 2010 - Paper 1

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The amount of iron in a newly developed, heat-resistant aluminium alloy is to be determined. An 80.50 g sample of alloy is dissolved in concentrated hydrochloric aci... show full transcript

Worked Solution & Example Answer:The amount of iron in a newly developed, heat-resistant aluminium alloy is to be determined - VCE - SSCE Chemistry - Question 1 - 2010 - Paper 1

Step 1

a. Write a balanced half-equation, including states, for the conversion of MnO₄⁻ ions, in an acidic solution, to Mn²⁺ ions.

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Answer

The balanced half-equation for the conversion of MnO₄⁻ ions to Mn²⁺ ions in an acidic solution is:

MnO4(aq)+8H+(aq)+5eMn2+(aq)+4H2O(l)\text{MnO}_4^{-}(aq) + 8 \text{H}^{+}(aq) + 5 \text{e}^{-} \rightarrow \text{Mn}^{2+}(aq) + 4 \text{H}_2\text{O}(l)

In this reaction, permanganate ions ( MnO₄⁻) are reduced to manganese ions ( Mn²⁺) in the presence of hydrogen ions ( H⁺) from the acidic solution.

Step 2

b. Calculate the average volume, in mL, of the concordant titres of the potassium permanganate solution.

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Answer

To find the average volume of the concordant titers, we first identify the concordant values from the titration results. The volumes used are:

  • 22.03 mL
  • 20.25 mL
  • 21.97 mL
  • 21.99 mL

The concordant volumes are the ones that are close to one another, which in this case are 21.97 mL and 21.99 mL. We now calculate the average:

Average Volume=21.97+21.992=21.98 mL\text{Average Volume} = \frac{21.97 + 21.99}{2} = 21.98 \text{ mL}

Thus, the average volume of the concordant titers is 21.98 mL.

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