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Nitrogen (II) oxide and chlorine react according to the equation 2NO(g) + Cl2(g) → 2NOCl(g); ΔH = -38 kJ mol⁻¹ The activation energy for the forward reaction is 62 kJ mol⁻¹ - VCE - SSCE Chemistry - Question 20 - 2004 - Paper 1

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Nitrogen-(II)-oxide-and-chlorine-react-according-to-the-equation--2NO(g)-+-Cl2(g)-→-2NOCl(g);-ΔH-=--38-kJ-mol⁻¹--The-activation-energy-for-the-forward-reaction-is-62-kJ-mol⁻¹-VCE-SSCE Chemistry-Question 20-2004-Paper 1.png

Nitrogen (II) oxide and chlorine react according to the equation 2NO(g) + Cl2(g) → 2NOCl(g); ΔH = -38 kJ mol⁻¹ The activation energy for the forward reaction is 62... show full transcript

Worked Solution & Example Answer:Nitrogen (II) oxide and chlorine react according to the equation 2NO(g) + Cl2(g) → 2NOCl(g); ΔH = -38 kJ mol⁻¹ The activation energy for the forward reaction is 62 kJ mol⁻¹ - VCE - SSCE Chemistry - Question 20 - 2004 - Paper 1

Step 1

The activation energy of the reverse reaction, in kJ mol⁻¹, is

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Answer

To find the activation energy of the reverse reaction, we use the relation:

Ea(reverse)=Ea(forward)+ΔHE_a (reverse) = E_a (forward) + |\Delta H|

Given:

  • The activation energy of the forward reaction, (E_a (forward) = 62 , kJ , mol^{-1})
  • The enthalpy change for the reaction, (\Delta H = -38 , kJ , mol^{-1}), thus (|\Delta H| = 38 , kJ , mol^{-1})

Calculating:

Ea(reverse)=62kJmol1+38kJmol1=100kJmol1E_a (reverse) = 62 \, kJ \, mol^{-1} + 38 \, kJ \, mol^{-1} = 100 \, kJ \, mol^{-1}

Therefore, the answer is D. 100.

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