An analysis is carried out on a sample of unknown gas - VCE - SSCE Chemistry - Question 14 - 2011 - Paper 1
Question 14
An analysis is carried out on a sample of unknown gas. The density of the gas is 2.86 grams per litre at STP.
The molecular formula of the gas is
A. HCl
B. Cl₂
C. NO... show full transcript
Worked Solution & Example Answer:An analysis is carried out on a sample of unknown gas - VCE - SSCE Chemistry - Question 14 - 2011 - Paper 1
Step 1
Calculate the Molar Mass using Density
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Answer
To determine the molecular formula of the gas, we first need to calculate the molar mass using the formula:
molarmass=density×PRT
Where:
Density = 2.86 grams per litre
At STP, R (ideal gas constant) = 0.0821 L·atm/(K·mol)
T (temperature) = 273.15 K
P (pressure) = 1 atm
Substituting the values:
molarmass=2.86×10.0821×273.15≈63.3 g/mol
Step 2
Determine the Molecular Formula based on Molar Mass
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Answer
Now, we have a calculated molar mass of approximately 63.3 g/mol.
Next, we need to compare this value with the molar masses of the given compounds:
HCl = 36.5 g/mol
Cl₂ = 70.9 g/mol
NO₂ = 46.0 g/mol
SO₂ = 64.1 g/mol
The closest match to our calculated molar mass is SO₂ (64.1 g/mol).
Therefore, the molecular formula of the gas is D. SO₂.