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The overall equation for the reaction occurring in this galvanic cell is A - VCE - SSCE Chemistry - Question 11 - 2011 - Paper 1

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The overall equation for the reaction occurring in this galvanic cell is A. Ag ext{(aq)} + Cu ext{(s)} → Ag ext{(s)} + Cu^{2+} ext{(aq)} B. 2Ag ext{(s)} + Cu^{2+} e... show full transcript

Worked Solution & Example Answer:The overall equation for the reaction occurring in this galvanic cell is A - VCE - SSCE Chemistry - Question 11 - 2011 - Paper 1

Step 1

The overall equation for the reaction occurring in this galvanic cell is

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Answer

To determine the overall reaction in a galvanic cell, we need to identify the half-reactions for both the oxidation and reduction processes, analyze the species involved, and then combine them appropriately.

  1. Identify Oxidation and Reduction Half-Reactions:

    • The oxidation half-reaction involves the oxidation of silver ions (Ag ext{(aq)}) to solid silver (Ag ext{(s)}).
    • The reduction half-reaction involves the reduction of copper ions (Cu^{2+} ext{(aq)}) to solid copper (Cu ext{(s)}).
  2. Write the Half-Reactions:

    • Oxidation: Ag+(aq)+eAg(s)Ag^{+}(aq) + e^{-} → Ag(s)
    • Reduction: Cu2+(aq)+2eCu(s)Cu^{2+}(aq) + 2e^{-} → Cu(s)
  3. Balance the Electrons:

    • To balance the electrons, you can multiply the oxidation half-reaction by 2: 2Ag+(aq)+2e2Ag(s)2Ag^{+}(aq) + 2e^{-} → 2Ag(s)
    • Now we can add both half-reactions:
      • Overall reaction: 2Ag+(aq)+Cu(s)2Ag(s)+Cu2+(aq)2Ag^{+}(aq) + Cu(s) → 2Ag(s) + Cu^{2+}(aq)
  4. Select the Correct Answer from Options:

    • The resulting equation matches option C: C. 2Ag^{+}(aq) + Cu(s) → 2Ag(s) + Cu^{2+}(aq).

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