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The lithium-ion battery is a secondary cell that is now widely used in portable electronic devices: In these batteries, lithium ions, Li^+, move through a special non-aqueous electrolyte between the two electrodes - VCE - SSCE Chemistry - Question 8 - 2016 - Paper 1

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The lithium-ion battery is a secondary cell that is now widely used in portable electronic devices: In these batteries, lithium ions, Li^+, move through a special no... show full transcript

Worked Solution & Example Answer:The lithium-ion battery is a secondary cell that is now widely used in portable electronic devices: In these batteries, lithium ions, Li^+, move through a special non-aqueous electrolyte between the two electrodes - VCE - SSCE Chemistry - Question 8 - 2016 - Paper 1

Step 1

During discharge, what is the polarity of the graphite electrode?

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Answer

During the discharge of a lithium-ion battery, the graphite electrode acts as the anode, which carries a negative charge. This happens because lithium ions, Li^+, move from the anode (graphite) to the cathode (LiCoO2) during discharge.

Step 2

Write the half-equation for the reaction that occurs at the cathode of a lithium-ion battery when it is recharged.

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Answer

The half-equation for the reaction at the cathode during recharging is:

Li++e+C6LiC6Li^+ + e^- + C_6 \rightarrow LiC_6

Step 3

Explain why and justify your answer with the use of appropriate equations.

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Answer

Lithium metal must not be in contact with water because it reacts vigorously with water, potentially leading to a fire or explosion. The reaction can be represented as:

2Li_s + 2H_2O_{(l)} \rightarrow 2LiOH_{(aq)} + H_2_{(g)}

Hydrogen gas is produced as a byproduct, which is highly flammable. Therefore, to prevent any dangerous reactions, lithium metal should be kept dry.

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