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Consider the following chemical equations: 2NO₂(g) → 2NO(g) + O₂(g) ΔHf = +14 kJ mol⁻¹ NO(g) + CO(g) → CO₂(g) + NO(g) ΔHf = -226 kJ mol⁻¹ 2NO₂(g) → N₂O₄(g) ΔHf = -57 kJ mol⁻¹ N₂(g) + O₂(g) → 2NO(g) ΔHf = +181 kJ mol⁻¹ Which one of the following graphs is consistent with the chemical equations above? - VCE - SSCE Chemistry - Question 18 - 2021 - Paper 1

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Question 18

Consider-the-following-chemical-equations:--2NO₂(g)-→-2NO(g)-+-O₂(g)--ΔHf-=-+14-kJ-mol⁻¹-NO(g)-+-CO(g)-→-CO₂(g)-+-NO(g)--ΔHf-=--226-kJ-mol⁻¹-2NO₂(g)-→-N₂O₄(g)--ΔHf-=--57-kJ-mol⁻¹-N₂(g)-+-O₂(g)-→-2NO(g)--ΔHf-=-+181-kJ-mol⁻¹--Which-one-of-the-following-graphs-is-consistent-with-the-chemical-equations-above?-VCE-SSCE Chemistry-Question 18-2021-Paper 1.png

Consider the following chemical equations: 2NO₂(g) → 2NO(g) + O₂(g) ΔHf = +14 kJ mol⁻¹ NO(g) + CO(g) → CO₂(g) + NO(g) ΔHf = -226 kJ mol⁻¹ 2NO₂(g) → N₂O₄(g) ΔHf =... show full transcript

Worked Solution & Example Answer:Consider the following chemical equations: 2NO₂(g) → 2NO(g) + O₂(g) ΔHf = +14 kJ mol⁻¹ NO(g) + CO(g) → CO₂(g) + NO(g) ΔHf = -226 kJ mol⁻¹ 2NO₂(g) → N₂O₄(g) ΔHf = -57 kJ mol⁻¹ N₂(g) + O₂(g) → 2NO(g) ΔHf = +181 kJ mol⁻¹ Which one of the following graphs is consistent with the chemical equations above? - VCE - SSCE Chemistry - Question 18 - 2021 - Paper 1

Step 1

Identify the Reaction Type

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Answer

The reactions provided can be classified into exothermic and endothermic processes. Notably, the reaction with ΔHf = -226 kJ mol⁻¹ is highly exothermic, indicating that it releases a significant amount of energy.

Step 2

Analyze the Graphs

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Answer

The appropriate graph should depict changes in enthalpy (kJ mol⁻¹) through the progress of the reaction. For exothermic reactions, we expect a drop in enthalpy, starting from reactants and proceeding towards products. The energy peak suggests an activation energy, leading to the products being at a lower enthalpy compared to the reactants.

Step 3

Determine Consistency with Given Equations

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Answer

Given the details of the reactions, the graph must reflect the energy changes indicated by the ΔH values. The graph corresponding to option C must exhibit the correct energy profile showing a drop due to exothermic reactions, consistent with the provided chemical equations.

Step 4

Final Answer

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Answer

The correct graph that aligns with the chemical equations above is option C.

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