A classroom experiment was set up to simulate the industrial extraction of zinc metal from an aqueous solution of zinc ions by electrolysis - VCE - SSCE Chemistry - Question 7 - 2009 - Paper 1
Question 7
A classroom experiment was set up to simulate the industrial extraction of zinc metal from an aqueous solution of zinc ions by electrolysis. In this experiment 150 m... show full transcript
Worked Solution & Example Answer:A classroom experiment was set up to simulate the industrial extraction of zinc metal from an aqueous solution of zinc ions by electrolysis - VCE - SSCE Chemistry - Question 7 - 2009 - Paper 1
Step 1
Write a half-equation for the oxidation reaction.
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Answer
In an electrolysis reaction involving zinc sulfate (ZnSO₄), zinc ions ( ext{Zn}^{2+} ext{(aq)}) are reduced to form zinc metal (Zn). The oxidation half-reaction occurs at the anode where water is oxidized. The half-equation for this reaction is:
ightarrow ext{O}_2 + 4 ext{H}^+ + 4e^-$$
Step 2
Calculate the electric current, in A, supplied to the cell during the electrolysis.
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Answer
To determine the electric current supplied during electrolysis, we can use the following steps:
Calculate the moles of zinc produced:
The molar mass of zinc (Zn) is approximately 65.4 g/mol. Thus, for 0.900 g of zinc:
extmolesofZn=65.4extg/mol0.900extg=0.01376extmol
Determine the number of electrons transferred (n):
From the half-reaction, each mole of Zn produces 2 moles of electrons:
n=2imes0.01376extmol=0.02752extmole−
Calculate the total charge (Q):
Using Faraday's constant (F = 96500 C/mol), the total charge can be calculated as:
Q=nimesF=0.02752extmol(96500extC/mol)=2656.00extC
Calculate the current (I):
The time (t) is given as 30.0 minutes (or 1800 seconds):
I=tQ=1800exts2656extC=1.477extA
Express the answer in appropriate significant figures:
The final answer, rounded to three significant figures, is: