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The molar heat of combustion of pentan-1-ol, C5H11OH, is 3329 kJ mol⁻¹ - VCE - SSCE Chemistry - Question 25 - 2018 - Paper 1

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The molar heat of combustion of pentan-1-ol, C5H11OH, is 3329 kJ mol⁻¹. M(C5H11OH) = 88.0 g mol⁻¹ The mass of C5H11OH, in tonnes, required to produce 10800 MJ of en... show full transcript

Worked Solution & Example Answer:The molar heat of combustion of pentan-1-ol, C5H11OH, is 3329 kJ mol⁻¹ - VCE - SSCE Chemistry - Question 25 - 2018 - Paper 1

Step 1

Calculate the energy required in kJ

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Answer

To convert 10800 MJ into kJ, use the conversion factor (1 MJ = 1000 kJ):

10800extMJ=10800imes1000=10800000extkJ10800 ext{ MJ} = 10800 imes 1000 = 10800000 ext{ kJ}

Step 2

Determine the amount of substance needed in moles

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Using the molar heat of combustion, the number of moles required can be calculated:

n=EnergyMolar Heat of Combustion=10800000extkJ3329extkJmol13243.52extmoln = \frac{\text{Energy}}{\text{Molar Heat of Combustion}} = \frac{10800000 ext{ kJ}}{3329 ext{ kJ mol}^{-1}} \approx 3243.52 ext{ mol}

Step 3

Calculate the total mass required

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Now calculate the mass using the molar mass of C5H11OH:

mass=n×M=3243.52extmol×88.0extgmol1285395.76extg\text{mass} = n \times M = 3243.52 ext{ mol} \times 88.0 ext{ g mol}^{-1} \approx 285395.76 ext{ g}

Step 4

Convert the mass to tonnes

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Finally, convert grams to tonnes (1 tonne = 1000 kg = 1000000 g):

mass in tonnes=285395.76extg10000000.2854exttonnes\text{mass in tonnes} = \frac{285395.76 ext{ g}}{1000000} \approx 0.2854 ext{ tonnes}

Step 5

Select the closest answer

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Answer

The closest answer to the calculated value of approximately 0.286 tonnes is:

B. 0.286

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