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Consider the following chemical equations: 2NO2(g) → 2NO(g) + O2(g) ΔHf = +14 kJ mol⁻¹ NO(g) + CO(g) → CO2(g) + NO(g) ΔHf = -226 kJ mol⁻¹ 2NO(g) → N2O4(g) ΔHf = -57 kJ mol⁻¹ N2(g) + O2(g) → 2NO(g) ΔHf = +181 kJ mol⁻¹ Which one of the following graphs is consistent with the chemical equations above? - VCE - SSCE Chemistry - Question 18 - 2021 - Paper 1

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Question 18

Consider-the-following-chemical-equations:--2NO2(g)-→-2NO(g)-+-O2(g)--ΔHf-=-+14-kJ-mol⁻¹-NO(g)-+-CO(g)-→-CO2(g)-+-NO(g)--ΔHf-=--226-kJ-mol⁻¹-2NO(g)-→-N2O4(g)--ΔHf-=--57-kJ-mol⁻¹-N2(g)-+-O2(g)-→-2NO(g)--ΔHf-=-+181-kJ-mol⁻¹--Which-one-of-the-following-graphs-is-consistent-with-the-chemical-equations-above?-VCE-SSCE Chemistry-Question 18-2021-Paper 1.png

Consider the following chemical equations: 2NO2(g) → 2NO(g) + O2(g) ΔHf = +14 kJ mol⁻¹ NO(g) + CO(g) → CO2(g) + NO(g) ΔHf = -226 kJ mol⁻¹ 2NO(g) → N2O4(g) ΔHf = ... show full transcript

Worked Solution & Example Answer:Consider the following chemical equations: 2NO2(g) → 2NO(g) + O2(g) ΔHf = +14 kJ mol⁻¹ NO(g) + CO(g) → CO2(g) + NO(g) ΔHf = -226 kJ mol⁻¹ 2NO(g) → N2O4(g) ΔHf = -57 kJ mol⁻¹ N2(g) + O2(g) → 2NO(g) ΔHf = +181 kJ mol⁻¹ Which one of the following graphs is consistent with the chemical equations above? - VCE - SSCE Chemistry - Question 18 - 2021 - Paper 1

Step 1

A. Analyze the first reaction: 2NO2(g) → 2NO(g) + O2(g)

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Answer

This reaction has a positive enthalpy change (+14 kJ mol⁻¹), indicating it is endothermic. The graph should show an increase in enthalpy from the reactants to the products.

Step 2

B. Analyze the second reaction: NO(g) + CO(g) → CO2(g) + NO(g)

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Answer

This reaction has a significantly negative enthalpy change (-226 kJ mol⁻¹), indicating it is highly exothermic. The graph should show a notable dip in enthalpy as the reaction progresses.

Step 3

C. Analyze the third reaction: 2NO(g) → N2O4(g)

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Answer

This reaction is exothermic with a negative enthalpy change (-57 kJ mol⁻¹), suggesting that the graph should show a decrease in enthalpy upon formation of the products.

Step 4

D. Analyze the fourth reaction: N2(g) + O2(g) → 2NO(g)

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Answer

This reaction has a positive enthalpy change (+181 kJ mol⁻¹), indicating an endothermic process. The graph will depict an increase in enthalpy from reactants to products.

Step 5

E. Determine the best graph: Graph C

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Answer

Given that the endothermic and exothermic reactions reflect a combination of enthalpic changes, graph C, which shows one endothermic and one exothermic process, is consistent with the chemical equations. Thus, the answer is C.

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