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The following reactions occur spontaneously as written: 2Cr^{2+}(aq) + Co^{2+}(aq) → 2Cr^{3+}(aq) + Co(s) Co(s) + Pb^{2+}(aq) → Co^{2+}(aq) + Pb(s) Fe(s) + 2Cr^{3+}(aq) → Fe^{2+}(aq) + 2Cr^{2+}(aq) Using this information, predict which one of the following pairs of reactants will react spontaneously - VCE - SSCE Chemistry - Question 17 - 2008 - Paper 1

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Question 17

The-following-reactions-occur-spontaneously-as-written:--2Cr^{2+}(aq)-+-Co^{2+}(aq)-→-2Cr^{3+}(aq)-+-Co(s)--Co(s)-+-Pb^{2+}(aq)-→-Co^{2+}(aq)-+-Pb(s)--Fe(s)-+-2Cr^{3+}(aq)-→-Fe^{2+}(aq)-+-2Cr^{2+}(aq)--Using-this-information,-predict-which-one-of-the-following-pairs-of-reactants-will-react-spontaneously-VCE-SSCE Chemistry-Question 17-2008-Paper 1.png

The following reactions occur spontaneously as written: 2Cr^{2+}(aq) + Co^{2+}(aq) → 2Cr^{3+}(aq) + Co(s) Co(s) + Pb^{2+}(aq) → Co^{2+}(aq) + Pb(s) Fe(s) + 2Cr^{3... show full transcript

Worked Solution & Example Answer:The following reactions occur spontaneously as written: 2Cr^{2+}(aq) + Co^{2+}(aq) → 2Cr^{3+}(aq) + Co(s) Co(s) + Pb^{2+}(aq) → Co^{2+}(aq) + Pb(s) Fe(s) + 2Cr^{3+}(aq) → Fe^{2+}(aq) + 2Cr^{2+}(aq) Using this information, predict which one of the following pairs of reactants will react spontaneously - VCE - SSCE Chemistry - Question 17 - 2008 - Paper 1

Step 1

A. Co(s) + Fe^{2+}(aq)

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Answer

To determine if these reactants will react spontaneously, we need to look at the potential for Co(s) to reduce Fe^{2+}(aq). Co is below Fe in the activity series, meaning it cannot reduce Fe^{2+}(aq) spontaneously.

Step 2

B. Cr^{2+}(aq) + Fe^{2+}(aq)

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Answer

Cr^{2+}(aq) can reduce Fe^{2+}(aq) as Cr is a stronger reducing agent. However, it depends on the specific standard reduction potentials which are not provided, so further analysis is necessary, but generally, it is not favorable spontaneously.

Step 3

C. Cr^{2+}(aq) + Pb^{2+}(aq)

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Answer

Based on the provided reactions, Cr^{2+}(aq) can reduce Pb^{2+}(aq) because Pb is lower in activity than Cr, thus indicating that this reaction occurs spontaneously.

Step 4

D. Pb(s) + Co^{2+}(aq)

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Answer

Pb(s) cannot react spontaneously with Co^{2+}(aq) since Pb is a weaker reducing agent compared to Co, as seen in the provided equations.

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