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a. Use information from the electrochemical series in the Data Book to write a balanced overall equation that shows hydrogen peroxide, H₂O₂, reacting as a reductant - VCE - SSCE Chemistry - Question 1 - 2009 - Paper 1

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a. Use information from the electrochemical series in the Data Book to write a balanced overall equation that shows hydrogen peroxide, H₂O₂, reacting as a reductant.... show full transcript

Worked Solution & Example Answer:a. Use information from the electrochemical series in the Data Book to write a balanced overall equation that shows hydrogen peroxide, H₂O₂, reacting as a reductant - VCE - SSCE Chemistry - Question 1 - 2009 - Paper 1

Step 1

Use information from the electrochemical series in the Data Book to write a balanced overall equation that shows hydrogen peroxide, H₂O₂, reacting as a reductant.

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Answer

The balanced overall equation showing hydrogen peroxide acting as a reductant can be expressed as follows:

2H2O2(aq)+2Fe3+(aq)2H+(aq)+2Fe2+(aq)+O2(g)2 H_2O_2 (aq) + 2 Fe^{3+} (aq) \rightarrow 2 H^+ (aq) + 2 Fe^{2+} (aq) + O_2 (g)

In this reaction, hydrogen peroxide is oxidized while the Fe³⁺ ions are reduced.

Step 2

Provide one possible chemical reason that explains why the predicted reaction was not observed.

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Answer

One possible reason for the lack of reaction between Cu²⁺ ions and H₂ gas is that the standard reduction potential of Cu²⁺/Cu is higher than that of H⁺/H₂. This means that H₂ does not have a sufficient driving force to reduce Cu²⁺ to Cu, thus no reaction occurs.

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