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One method of analysing the manganese content of steel is to dissolve the steel in nitric acid; producing a solution of manganese(II) ions, Mn²⁺(aq) - VCE - SSCE Chemistry - Question 2 - 2008 - Paper 1

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One method of analysing the manganese content of steel is to dissolve the steel in nitric acid; producing a solution of manganese(II) ions, Mn²⁺(aq). The Mn²⁺(aq) i... show full transcript

Worked Solution & Example Answer:One method of analysing the manganese content of steel is to dissolve the steel in nitric acid; producing a solution of manganese(II) ions, Mn²⁺(aq) - VCE - SSCE Chemistry - Question 2 - 2008 - Paper 1

Step 1

i. Give a half equation for the conversion of IO₄⁻(aq) into IO₃⁻(aq) in acid solution.

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Answer

The half-equation for the reduction of iodate ions is as follows:

IO4(aq)+2H+(aq)+2eIO3(aq)+H2O(l)IO₄⁻(aq) + 2H^+(aq) + 2e^- \rightarrow IO₃⁻(aq) + H₂O(l)

This equation shows the iodate ion being reduced to iodate in the presence of protons, with the transfer of electrons.

Step 2

ii. Is the IO₄⁻(aq) ion acting as an oxidant or reductant? Explain your choice.

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Answer

The IO₄⁻(aq) ion is acting as an oxidant. This is because it facilitates the oxidation of Mn²⁺ to MnO₄⁻, indicating that it has the ability to accept electrons from another species. As IO₄⁻ is reduced in the process, its oxidation state decreases, confirming its role as an oxidizing agent.

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