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The transition metal vanadium exists in a range of different oxidation states - VCE - SSCE Chemistry - Question 11 - 2002 - Paper 1

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The transition metal vanadium exists in a range of different oxidation states. Two vanadium species are VO^{2+} and VO_{2}^{+}. The oxidation states of vanadium in t... show full transcript

Worked Solution & Example Answer:The transition metal vanadium exists in a range of different oxidation states - VCE - SSCE Chemistry - Question 11 - 2002 - Paper 1

Step 1

Determine the oxidation state of VO^{2+}

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Answer

In the VO^{2+} ion, we have one vanadium atom (V) and an overall charge of +2. Let the oxidation state of vanadium be denoted as x. The oxidation state of oxygen (O) is -2. Thus, we can set up the equation:

x+(2)=+2x + (-2) = +2

Solving for x:

x=+2+2=+4x = +2 + 2 = +4

So, the oxidation state of vanadium in VO^{2+} is +4.

Step 2

Determine the oxidation state of VO_{2}^{+}

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Answer

For the VO_{2}^{+} ion, we have one vanadium atom and an overall charge of +1. Again, let the oxidation state of vanadium be denoted as x. The oxidation state of each oxygen is -2, and since there are two oxygen atoms, the equation will be:

x+2(2)=+1x + 2(-2) = +1

Simplifying this gives us:

x4=+1x - 4 = +1

Solving for x:

x=+1+4=+5x = +1 + 4 = +5

Thus, the oxidation state of vanadium in VO_{2}^{+} is +5.

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