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The following structure shows part of a polypeptide: OH I COO–H I CH2– H I I N–C–C–C– H H I I I H COO– CH2–COOH At a particular pH, an amino acid in solution can exist as ions that have both a negative and positive charge - VCE - SSCE Chemistry - Question 6 - 2009 - Paper 1

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Question 6

The-following-structure-shows-part-of-a-polypeptide:--OH---------I--------COO–H--I--CH2–-------H--I---I-----N–C–C–C–-------H---H--I---I------I----H--COO–--CH2–COOH--At-a-particular-pH,-an-amino-acid-in-solution-can-exist-as-ions-that-have-both-a-negative-and-positive-charge-VCE-SSCE Chemistry-Question 6-2009-Paper 1.png

The following structure shows part of a polypeptide: OH I COO–H I CH2– H I I N–C–C–C– H H I I I H COO– CH2–COOH ... show full transcript

Worked Solution & Example Answer:The following structure shows part of a polypeptide: OH I COO–H I CH2– H I I N–C–C–C– H H I I I H COO– CH2–COOH At a particular pH, an amino acid in solution can exist as ions that have both a negative and positive charge - VCE - SSCE Chemistry - Question 6 - 2009 - Paper 1

Step 1

Name the amino acids that make up this section of the polypeptide:

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Answer

The amino acids present in the polypeptide section are

  • Serine
  • Glycine
  • Aspartic acid.

Step 2

Choose one of the amino acids in this section of polypeptide and draw the structure of its zwitterion clearly showing all bonds:

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Answer

For example, using Glycine:

     H
      |   
H2N–C–COO⁻  
      |  
     H

In the zwitterionic form, glycine has a positively charged amino group (–NH3⁺) and a negatively charged carboxylate group (–COO⁻), which balances the overall charge.

Step 3

Give the names of two carbon compounds that can be used to synthesise this ester:

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Answer

The two carbon compounds that can be used for synthesising the ester in raspberry flavouring are:

  • Methanol
  • Butanoic acid

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