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Esters are the basis of many naturally occurring odours and are therefore widely used in the creation of artificial flavours - VCE - SSCE Chemistry - Question 3 - 2003 - Paper 1

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Esters are the basis of many naturally occurring odours and are therefore widely used in the creation of artificial flavours. Methyl butanoate is a component of the ... show full transcript

Worked Solution & Example Answer:Esters are the basis of many naturally occurring odours and are therefore widely used in the creation of artificial flavours - VCE - SSCE Chemistry - Question 3 - 2003 - Paper 1

Step 1

a. Give a simple structure for the ester methyl butanoate.

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Answer

The structure of methyl butanoate can be represented as:

      O
      ||
CH3-CH2-CH2-C-O-CH3

This ester's structure comprises a butanoate group linked to a methyl group.

Step 2

b. Using 1-butanol and methanol as starting materials give chemical equations showing the steps in the preparation of methyl butanoate. Give the name of any catalyst used.

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Answer

  1. Conversion of 1-butanol to butanoic acid:

    CH3-CH2-CH2-CH2-OH + [O] → CH3-CH2-CH2-COOH + H2O

    Here, 1-butanol is oxidised to butanoic acid using oxidising agents like chromium trioxide.

  2. Formation of methyl butanoate:

    CH3-CH2-COOH + CH3OH → CH3-CH2-COO-CH3 + H2O

    This reaction occurs via a condensation reaction (esterification), combining butanoic acid with methanol.

Catalyst used:

  • Sulfuric acid (H2SO4) is often used as a catalyst for the esterification reaction.

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