For this reaction at equilibrium, which combination of temperature and pressure would give the greatest equilibrium yield of products?
W(g) + X(g) ⇌ 2Y(g) + Z(g)
ΔH = +447 kJ mol⁻¹
A High pressure and high temperature
B High pressure and low temperature
C Low pressure and high temperature
D Low pressure and low temperature - AQA - A-Level Chemistry - Question 34 - 2018 - Paper 3
Question 34
For this reaction at equilibrium, which combination of temperature and pressure would give the greatest equilibrium yield of products?
W(g) + X(g) ⇌ 2Y(g) + Z(g)
... show full transcript
Worked Solution & Example Answer:For this reaction at equilibrium, which combination of temperature and pressure would give the greatest equilibrium yield of products?
W(g) + X(g) ⇌ 2Y(g) + Z(g)
ΔH = +447 kJ mol⁻¹
A High pressure and high temperature
B High pressure and low temperature
C Low pressure and high temperature
D Low pressure and low temperature - AQA - A-Level Chemistry - Question 34 - 2018 - Paper 3
Step 1
High pressure and high temperature
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Answer
This combination would favor the production of products; however, the reaction is endothermic (ΔH = +447 kJ mol⁻¹), which means higher temperatures are actually beneficial for shifting the equilibrium to the right.
Step 2
High pressure and low temperature
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Answer
High pressure will favor the side with fewer gas molecules. However, low temperatures are not ideal for an endothermic reaction.
Step 3
Low pressure and high temperature
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Answer
Low pressure is not favorable since it could lead to lower yields of products, and although high temperature favors the endothermic reaction, the pressure factor is crucial.
Step 4
Low pressure and low temperature
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Answer
This combination is the least favorable as both factors work against producing the products.