The equation for the reaction between sulfur dioxide and oxygen is shown - AQA - A-Level Chemistry - Question 11 - 2019 - Paper 3
Question 11
The equation for the reaction between sulfur dioxide and oxygen is shown.
$$2SO_{2}(g) + O_{2}(g) \rightleftharpoons 2SO_{3}(g)$$
In an experiment, 2.00 mol of sul... show full transcript
Worked Solution & Example Answer:The equation for the reaction between sulfur dioxide and oxygen is shown - AQA - A-Level Chemistry - Question 11 - 2019 - Paper 3
Step 1
Calculate the Change in Moles
96%
114 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
Initially, we have 2.00 mol of sulfur dioxide and 2.00 mol of oxygen. The balanced equation indicates that 2 moles of sulfur dioxide react with 1 mole of oxygen to produce 2 moles of sulfur trioxide.
Let 'x' be the amount of sulfur dioxide reacted. The stoichiometric ratios tell us that:
2 moles of SO₂ produce 2 moles of SO₃, so the amount of SO₃ will be 'x'.
The amount of O₂ consumed will be 'x/2' (since 1 mol of O₂ reacts with 2 mol of SO₂).
At equilibrium, we know:
Total amount of gases = 3.40 mol
Let’s represent the amounts at equilibrium:
Moles of SO₂ left = 2.00 - x
Moles of O₂ left = 2.00 - x/2
Moles of SO₃ produced = x
Step 2
Write the Total Mole Equation
99%
104 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
Now we write the total in terms of x:
(2.00−x)+(2.00−2x)+x=3.40
Simplifying this:
4.00−x+x−2x=3.40
This simplifies to:
4.00−2x=3.40
Isolating x gives:
2x=0.60⟹x=1.20
Step 3
Determine Moles of SO₃
96%
101 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
From our calculation, the moles of sulfur trioxide at equilibrium = 1.20 mol.
Now we can find the mole fraction of SO₃:
Mole fraction of SO3=Total molesMoles of SO3=3.401.20
Step 4
Calculate the Mole Fraction
98%
120 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
Calculating this gives:
Mole fraction of SO3=3.401.20≈0.353
Thus, the mole fraction of sulfur trioxide in the equilibrium mixture is approximately 0.353.