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Tetrafluoroethene is made from chlorodifluoromethane in this reversible reaction - AQA - A-Level Chemistry - Question 2 - 2022 - Paper 2

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Tetrafluoroethene is made from chlorodifluoromethane in this reversible reaction. \[ 2CHCl_2(g) \rightleftharpoons C_2F_4(g) + 2HCl(g) \] \[ \Delta H = +128\, kJ\, ... show full transcript

Worked Solution & Example Answer:Tetrafluoroethene is made from chlorodifluoromethane in this reversible reaction - AQA - A-Level Chemistry - Question 2 - 2022 - Paper 2

Step 1

Calculate the amount, in moles, of C₂F₄ and of HCl in the equilibrium mixture.

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Answer

Initial moles of CHCl₂F = 2.00 mol. At equilibrium, moles of CHCl₂F = 0.270 mol.

Change in moles of CHCl₂F = 2.00 mol - 0.270 mol = 1.73 mol.

From the balanced equation: [ 2CHCl_2F \rightarrow C_2F_4 + 2HCl ] 1 mole of C₂F₄ forms for every 2 moles of CHCl₂F that react, so:

[ \text{Moles of } C_2F_4 = \frac{1.73}{2} = 0.865 , \text{mol} ]

For HCl, 2 moles of HCl are produced for every 2 moles of CHCl₂F: [ \text{Moles of } HCl = 1.73 , \text{mol} ]

Step 2

Give an expression for Kc for this equilibrium.

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Answer

[ K_c = \frac{[C_2F_4][HCl]^2}{[CHCl_2F]^2} ]

Step 3

Calculate a value for Kc.

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Answer

Using equilibrium concentrations:

[ K_c = \frac{\left(\frac{0.865}{23.2}\right) \left(\frac{1.73}{23.2}\right)^2}{\left(\frac{0.270}{23.2}\right)^2} ]

Calculating values: [ K_c = 0.86 ] (rounded) with units of [ \text{dm}^{-6} \text{mol}^{-2} ]

Step 4

State and explain the effect of using a higher temperature on the equilibrium yield of tetrafluoroethene.

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Answer

Effect on yield: Yield would increase.

Explanation: Increasing the temperature shifts the equilibrium to favor the endothermic reaction, which is the forward reaction that produces tetrafluoroethene.

Step 5

State the environmental problem that chlorodifluoromethane can cause.

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Answer

Chlorodifluoromethane causes ozone depletion, leading to increased UV radiation and environmental damage.

Step 6

Give one reason why pentane does not cause this problem.

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Answer

Pentane does not contain C-Cl bonds which are responsible for ozone depletion.

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