This question is about the reactions of alkanes - AQA - A-Level Chemistry - Question 1 - 2018 - Paper 2
Question 1
This question is about the reactions of alkanes.
Alkanes can be used as fuels.
Give an equation for the combustion of heptane (C7H16) in an excess of oxygen.
Hept... show full transcript
Worked Solution & Example Answer:This question is about the reactions of alkanes - AQA - A-Level Chemistry - Question 1 - 2018 - Paper 2
Step 1
Give an equation for the combustion of heptane (C7H16) in an excess of oxygen.
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Answer
The balanced equation for the complete combustion of heptane in excess oxygen is:
C7H16+11O2→7CO2+8H2O
Step 2
Identify a suitable catalyst for this process.
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Answer
A suitable catalyst for the catalytic cracking of hexadecane is zeolite or aluminosilicate.
Step 3
Give one condition other than high temperature.
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One condition for the process is to operate under slight to moderate pressure.
Step 4
Give an equation for the catalytic cracking of one molecule of hexadecane to produce one molecule of heptane, one molecule of cyclohexane and one other product.
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Answer
The equation for the catalytic cracking of hexadecane can be represented as:
C16H34→C7H16+C6H12+C3H6
Step 5
Give equations for the propagation steps in the reaction of butane to form 2-chlorobutane.
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Answer
The propagation steps involved can be illustrated as follows:
C4H10+Cl2→C4H9Cl+HCl
C4H9Cl+Cl2→C4H8Cl2+HCl
Step 6
Identify the radical produced from this CFC that is responsible for the depletion of ozone in the atmosphere.
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The radical produced from the CFC (chlorofluorocarbon) that is responsible for ozone depletion is Cl· (Chlorine radical).
Step 7
Explain, with the aid of equations, why a single radical can cause the decomposition of many molecules of ozone.
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The chlorine radical can propagate the reaction that destroys ozone. The reaction sequence is as follows:
The chlorine radical reacts with ozone:
Cl⋅+O3→ClO⋅+O2
The chlorine monoxide radical can react with another ozone molecule:
ClO⋅+O→Cl⋅+O2
This shows that one chlorine radical can lead to the depletion of multiple ozone molecules through a chain reaction.