Polystyrene can be made from benzene in the series of steps shown - AQA - A-Level Chemistry - Question 6 - 2020 - Paper 2
Question 6
Polystyrene can be made from benzene in the series of steps shown.
**Step 1:** Benzene reacts with a suitable acylating agent.
**Step 2:** The organic product of... show full transcript
Worked Solution & Example Answer:Polystyrene can be made from benzene in the series of steps shown - AQA - A-Level Chemistry - Question 6 - 2020 - Paper 2
Step 1
State the type of reaction in step 1.
96%
114 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
The type of reaction in step 1 is acylation.
Step 2
Identify the reagent(s) and conditions needed for step 1.
99%
104 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
Reagents: Chloroacetic acid or Ethanoyl chloride.
Conditions: Anhydrous conditions, possibly using aluminum chloride as a catalyst.
Step 3
State the name of the mechanism for the reaction in step 2.
96%
101 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
The mechanism for the reaction in step 2 is nucleophilic addition.
Step 4
Identify the inorganic reagent needed for step 2.
98%
120 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
The inorganic reagent needed for step 2 is sodium borohydride (NaBH4).
Step 5
Name the organic product of step 2.
97%
117 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
The organic product of step 2 is 1-phenyl ethanol.
Step 6
Outline the mechanism for step 3.
97%
121 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
The mechanism for step 3 involves electrophilic substitution where the organic product undergoes a reaction with concentrated sulfuric acid, leading to the generation of a carbocation intermediate, followed by the loss of water and the formation of polystyrene.
Step 7
Draw the repeating unit of polystyrene.
96%
114 rated
Only available for registered users.
Sign up now to view full answer, or log in if you already have an account!
Answer
The repeating unit of polystyrene can be represented as follows:
C H
\ /
C
/ \
C H
/ \
C C
\ /
C H
\ /
C
This structure depicts the backbone of polystyrene with phenyl groups attached.