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This question is about some Group 7 compounds - AQA - A-Level Chemistry - Question 5 - 2019 - Paper 1

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This question is about some Group 7 compounds. Solid sodium chloride reacts with concentrated sulfuric acid. Give an equation for this reaction. State the role of... show full transcript

Worked Solution & Example Answer:This question is about some Group 7 compounds - AQA - A-Level Chemistry - Question 5 - 2019 - Paper 1

Step 1

Give an equation for this reaction.

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Answer

The reaction between solid sodium chloride (NaCl) and concentrated sulfuric acid (H₂SO₄) can be represented as:

NaCl+H2SO4NaHSO4+HClNaCl + H_2SO_4 \rightarrow NaHSO_4 + HCl

Step 2

State the role of the sulfuric acid in this reaction.

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Answer

The role of sulfuric acid in this reaction is that it acts as a proton donor (Bronsted-Lowry acid), donating protons to the chloride ions.

Step 3

For this reaction give an equation.

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Answer

When sodium bromide (NaBr) reacts with concentrated sulfuric acid, the equation is:

NaBr+H2SO4NaHSO4+HBrNaBr + H_2SO_4 \rightarrow NaHSO_4 + HBr

Step 4

Give one other observation.

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Answer

One other observation is the evolution of brown fumes of bromine gas (Br₂) during the reaction.

Step 5

State the role of the sulfuric acid.

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Answer

In this reaction, sulfuric acid serves as an oxidizing agent.

Step 6

Give the oxidation state of chlorine in NaClO, and in NaCl.

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Answer

In sodium hypochlorite (NaClO), the oxidation state of chlorine is +1. In sodium chloride (NaCl), the oxidation state of chlorine is -1.

Step 7

State, in terms of redox, what happens to chlorine in the reaction 05.3.

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Answer

In this reaction, chlorine is oxidized and also reduced, undergoing disproportionation.

Step 8

Give the formulas of D, E and F.

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Answer

The formulas are as follows:

  • D: AgBr
  • E: AgCl
  • F: Ag(NH₃)₂Cl

Step 9

Give an ionic equation to show the formation of E.

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Answer

The ionic equation for the formation of silver chloride (E) from silver nitrate and hydrochloric acid is:

Ag+(aq)+Cl(aq)AgCl(s)Ag^+ (aq) + Cl^- (aq) \rightarrow AgCl (s)

Step 10

Give an equation to show the conversion of D into G.

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Answer

The equation showing the conversion of silver bromide (D) into silver chloride (G) can be represented as:

AgBr+2NH3Ag(NH3)2++BrAgBr + 2NH_3 \rightarrow Ag(NH_3)_2^+ + Br^-

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