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This question is about elements in Period 3 and their compounds - AQA - A-Level Chemistry - Question 3 - 2021 - Paper 1

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This question is about elements in Period 3 and their compounds. 0 3.1 When a piece of sodium is added to 200 cm³ of water in a large beaker a vigorous reaction occ... show full transcript

Worked Solution & Example Answer:This question is about elements in Period 3 and their compounds - AQA - A-Level Chemistry - Question 3 - 2021 - Paper 1

Step 1

Give an equation, including state symbols, for the reaction of sodium with water.

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Answer

The balanced chemical equation for the reaction of sodium with water is:

2 \text{Na}_{(s)} + 2 \text{H}_2\text{O}_{(l)} \rightarrow 2 \text{NaOH}_{(aq)} + \text{H}_2_{(g)}

Step 2

Suggest why it is dangerous to react a similar piece of sodium with 10 cm³ of water in a boiling tube.

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Answer

It is dangerous to react a similar piece of sodium with 10 cm³ of water in a boiling tube because of the exothermic nature of the reaction. A small volume of water may rapidly evaporate, leading to a potential explosion as the generated hydrogen gas can ignite due to the heat from the reaction.

Step 3

Give an equation for the reaction of phosphorus(V) oxide with water.

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Answer

The balanced equation for the reaction of phosphorus(V) oxide with water is:

\text{P}_2\text{O}_5_{(s)} + 6 \text{H}_2\text{O}_{(l)} \rightarrow 2 \text{H}_3\text{PO}_4_{(aq)}

Step 4

Suggest a pH for the solution formed.

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Answer

The pH of the solution formed from the reaction of phosphorus(V) oxide with water is expected to be acidic, typically around pH 1 to 2, as it forms phosphoric acid.

Step 5

Explain, in terms of crystal structure and bonding, why silicon(IV) oxide has a higher melting point than phosphorus(V) oxide.

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Answer

Silicon(IV) oxide has a higher melting point than phosphorus(V) oxide because of its giant covalent structure where each silicon atom is bonded to four oxygen atoms in a tetrahedral arrangement, creating a strong network of covalent bonds that require a large amount of energy to break. In contrast, phosphorus(V) oxide has a molecular or simple covalent structure with weaker Van der Waals forces between molecules, allowing it to melt at a lower temperature.

Step 6

Give the formula for this oxide.

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Answer

The formula for the oxide that is insoluble in water is likely extSiO2 ext{SiO}_2 (silicon dioxide).

Step 7

Give an equation for the reaction of this oxide with sulfuric acid.

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Answer

The reaction of silicon dioxide with sulfuric acid can be represented as:

\text{SiO}_2_{(s)} + 2 \text{H}_2\text{SO}_4_{(l)} \rightarrow \text{Si(SO}_4\text{)}_{(aq)} + 2 \text{H}_2\text{O}_{(l)}

Step 8

Give the formula of a hydroxide of an element in Period 3 used in medicine.

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Answer

The formula for the hydroxide of an element in Period 3 that is used in medicine is extAl(OH)3 ext{Al(OH)}_3 (aluminum hydroxide).

Step 9

Identify the element in Period 3, from sodium to chlorine, that has the largest atomic radius.

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Answer

The element in Period 3 that has the largest atomic radius is sodium (Na).

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