This question is about elements in Period 3 and their compounds - AQA - A-Level Chemistry - Question 3 - 2021 - Paper 1
Question 3
This question is about elements in Period 3 and their compounds.
0 3.1
When a piece of sodium is added to 200 cm³ of water in a large beaker a vigorous reaction occ... show full transcript
Worked Solution & Example Answer:This question is about elements in Period 3 and their compounds - AQA - A-Level Chemistry - Question 3 - 2021 - Paper 1
Step 1
Give an equation, including state symbols, for the reaction of sodium with water.
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Answer
The balanced chemical equation for the reaction of sodium with water is:
Suggest why it is dangerous to react a similar piece of sodium with 10 cm³ of water in a boiling tube.
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It is dangerous to react a similar piece of sodium with 10 cm³ of water in a boiling tube because of the exothermic nature of the reaction. A small volume of water may rapidly evaporate, leading to a potential explosion as the generated hydrogen gas can ignite due to the heat from the reaction.
Step 3
Give an equation for the reaction of phosphorus(V) oxide with water.
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Answer
The balanced equation for the reaction of phosphorus(V) oxide with water is:
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Answer
The pH of the solution formed from the reaction of phosphorus(V) oxide with water is expected to be acidic, typically around pH 1 to 2, as it forms phosphoric acid.
Step 5
Explain, in terms of crystal structure and bonding, why silicon(IV) oxide has a higher melting point than phosphorus(V) oxide.
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Silicon(IV) oxide has a higher melting point than phosphorus(V) oxide because of its giant covalent structure where each silicon atom is bonded to four oxygen atoms in a tetrahedral arrangement, creating a strong network of covalent bonds that require a large amount of energy to break. In contrast, phosphorus(V) oxide has a molecular or simple covalent structure with weaker Van der Waals forces between molecules, allowing it to melt at a lower temperature.
Step 6
Give the formula for this oxide.
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The formula for the oxide that is insoluble in water is likely extSiO2 (silicon dioxide).
Step 7
Give an equation for the reaction of this oxide with sulfuric acid.
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Answer
The reaction of silicon dioxide with sulfuric acid can be represented as: