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A student does an experiment to determine a value for the enthalpy of combustion of heptane - AQA - A-Level Chemistry - Question 3 - 2021 - Paper 2

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A student does an experiment to determine a value for the enthalpy of combustion of heptane. Figure 2 shows some of the apparatus used. Design a table to record all... show full transcript

Worked Solution & Example Answer:A student does an experiment to determine a value for the enthalpy of combustion of heptane - AQA - A-Level Chemistry - Question 3 - 2021 - Paper 2

Step 1

Design a table to record all the readings necessary to determine an experimental value for the enthalpy of combustion for heptane in this experiment.

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Answer

ParameterUnit (if applicable)
Initial Temperature°C
Final Temperature°C
Mass of Calorimeterg
Mass of Heptaneg
Time taken for reactionminutes

Step 2

Suggest two disadvantages of using a glass beaker on a tripod and gauze.

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Answer

  1. Glass is a poorer conductor than copper, which may result in inefficient heat transfer during the combustion process.

  2. Using a tripod and gauze would create a height above the flame, causing heat loss to the surroundings, leading to less accurate results.

Step 3

Suggest two reasons why the value of enthalpy of combustion from this experiment is less exothermic than a data book value.

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Answer

  1. Heat loss to the surroundings or the copper/calorimeter during the experiment may result in lower measured heat output.

  2. Incomplete combustion of heptane could lead to reduced energy release compared to the theoretical value.

Step 4

Suggest one addition to this apparatus that would improve the accuracy of the enthalpy value obtained.

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Answer

Using a wind shield to reduce heat loss due to air currents would help maintain more accurate temperature readings.

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