The rate expression for the reaction between X and Y is
rate = k[X][Y]
Which statement is correct?
A The rate constant has units mol⁻¹ dm³ s⁻¹
B The rate of the reaction is halved if the concentration of X is halved and the concentration of Y is doubled - AQA - A-Level Chemistry - Question 12 - 2020 - Paper 3
Question 12
The rate expression for the reaction between X and Y is
rate = k[X][Y]
Which statement is correct?
A The rate constant has units mol⁻¹ dm³ s⁻¹
B The rate of the r... show full transcript
Worked Solution & Example Answer:The rate expression for the reaction between X and Y is
rate = k[X][Y]
Which statement is correct?
A The rate constant has units mol⁻¹ dm³ s⁻¹
B The rate of the reaction is halved if the concentration of X is halved and the concentration of Y is doubled - AQA - A-Level Chemistry - Question 12 - 2020 - Paper 3
Step 1
A The rate constant has units mol⁻¹ dm³ s⁻¹
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Answer
The rate constant, k, in the rate expression can take various units depending on the overall order of the reaction. For this specific rate law, it has units of mol⁻¹ dm³ s⁻¹ consistent with a second-order reaction involving two reactants.
Step 2
B The rate of the reaction is halved if the concentration of X is halved and the concentration of Y is doubled.
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Answer
This statement is incorrect because if the concentration of X is halved, the rate will also decrease significantly, whereas doubling the concentration of Y will not completely counterbalance the reduced rate from X.
Step 3
C The rate increases by a factor of 16 if the concentration of X is tripled and the concentration of Y is doubled.
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Answer
This statement is also incorrect. If [X] is tripled, it contributes a factor of 3, and if [Y] is doubled, it contributes a factor of 2. Thus, the total factor is 3 * 2 = 6, not 16.
Step 4
D The rate constant is independent of temperature.
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Answer
The rate constant is dependent on temperature, typically described by the Arrhenius equation. Therefore, this statement is false.