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This question is about chemical reactions and electricity - AQA - GCSE Chemistry - Question 7 - 2021 - Paper 1

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This question is about chemical reactions and electricity. Explain the difference between the processes in electrolysis and in a chemical cell. Electrolysis uses e... show full transcript

Worked Solution & Example Answer:This question is about chemical reactions and electricity - AQA - GCSE Chemistry - Question 7 - 2021 - Paper 1

Step 1

Explain the difference between the processes in electrolysis and in a chemical cell.

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Answer

Electrolysis involves using electricity to drive a non-spontaneous chemical reaction, allowing ions to move and react to produce products, such as gases. In contrast, a chemical cell generates electricity through spontaneous chemical reactions, where reactants undergo oxidation and reduction, producing an electric current.

Step 2

Complete the half equation for the production of bromine.

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Answer

The half equation is:

extBrBr2+2e ext{Br}^- \rightarrow \text{Br}_2 + 2 e^-

Step 3

Complete Table 4 to show the product at each electrode.

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Answer

Salt solutionProduct at positive electrodeProduct at negative electrode
Copper nitrateOxygenCopper
Potassium iodideIodineHydrogen

Step 4

Suggest how the students could find the total mass of copper produced.

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Answer

To find the total mass of copper, the students should filter the mixture, wash and dry the copper residue, weigh the copper collected, and then add this mass to the increase in mass of the electrode.

Step 5

How do the results in Figure 5 support the conclusion that the total mass of copper produced is directly proportional to the time?

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Answer

For a given current, the results show a straight line through the origin, indicating that the total mass of copper produced increases linearly with time. Thus, when the time doubles, the mass of copper produced also doubles, confirming direct proportionality.

Step 6

How do the results in Figure 5 support the conclusion that the total mass of copper produced is directly proportional to the current?

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Answer

The graph shows that for a fixed time, if the current is increased, the mass produced also increases. Specifically, when the current is doubled, the mass doubles, which supports the conclusion of proportionality between mass produced and current.

Step 7

Suggest why the blue colour of the copper nitrate solution fades during the electrolysis.

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Answer

The blue colour fades because copper ions are discharged from the solution during the electrolysis, leading to a decrease in the concentration of copper ions in the solution.

Step 8

Determine the number of atoms of copper produced when copper nitrate solution is electrolyzed for 20 minutes at a current of 0.6 A.

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Answer

First, calculate the number of moles of copper produced:

Number of moles=0.2463.5=0.00378\text{Number of moles} = \frac{0.24}{63.5} = 0.00378

Next, calculate the number of atoms:

Number of atoms=0.00378×6.02×1023=2.28×1021\text{Number of atoms} = 0.00378 \times 6.02 \times 10^{23} = 2.28 \times 10^{21}

Thus, the answer is 2.28 × 10²¹.

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