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This question is about potassium and its compounds - AQA - GCSE Chemistry - Question 4 - 2017 - Paper 3

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This question is about potassium and its compounds. 4 (a) (i) Potassium reacts with water to produce potassium hydroxide solution and a gas. Figure 8 shows the ... show full transcript

Worked Solution & Example Answer:This question is about potassium and its compounds - AQA - GCSE Chemistry - Question 4 - 2017 - Paper 3

Step 1

Complete and balance the equation for the reaction.

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Answer

The balanced equation for the reaction of potassium with water is:

ightarrow 2 KOH + H_2$$ This indicates that two moles of potassium react with two moles of water to produce two moles of potassium hydroxide and one mole of hydrogen gas.

Step 2

Give two differences you would see between the reactions of potassium and lithium with water.

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Answer

  1. Reactivity: Potassium reacts more vigorously and quickly with water compared to lithium, producing a larger amount of gas.

  2. Flame Color: During the reaction, potassium produces a lilac flame due to the presence of potassium ions, while lithium does not.

Step 3

Describe how a student could do titrations to find the mean volume of potassium hydroxide solution which would neutralise 25.00 cm³ of nitric acid.

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Answer

  1. Setup: Fill a burette with the potassium hydroxide solution. Use a pipette to measure exactly 25.00 cm³ of nitric acid into a conical flask.

  2. Add Indicator: Add a few drops of a suitable pH indicator, such as phenolphthalein, to the nitric acid solution in the conical flask.

  3. Titration: Slowly add the potassium hydroxide solution from the burette to the nitric acid while swirling the flask until the indicator changes color.

  4. Record Volume: Take note of the final volume of potassium hydroxide used at the end of the titration.

  5. Repeat: Repeat the titration to determine a consistent mean volume, recording all relevant measurements.

Step 4

Calculate the concentration of the nitric acid.

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Answer

To calculate the concentration of nitric acid:

  1. Determine Moles of KOH:
    Volume of KOH = 26.25 cm³ = 0.02625 dm³
    Concentration of KOH = 0.20 moles/dm³
    Moles of KOH = concentration × volume = 0.20 × 0.02625 = 0.00525 moles

  2. Reaction Stoichiometry: From the balanced equation, 1 mole of KOH reacts with 1 mole of HNO₃, so moles of HNO₃ = 0.00525 moles.

  3. Calculate Concentration of HNO₃:

    Volume of HNO₃ = 25.00 cm³ = 0.02500 dm³
    Concentration = moles/volume = 0.00525 moles / 0.02500 dm³ = 0.21 moles/dm³.

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