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This question is about the reaction between hydrogen sulfide (H₂S) and oxygen - AQA - GCSE Chemistry - Question 8 - 2021 - Paper 1

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This question is about the reaction between hydrogen sulfide (H₂S) and oxygen. The equation for the reaction is: 2 H₂S(g) + 3 O₂(g) → 2 H₂O(g) + 2 SO₂(g) 1. What ... show full transcript

Worked Solution & Example Answer:This question is about the reaction between hydrogen sulfide (H₂S) and oxygen - AQA - GCSE Chemistry - Question 8 - 2021 - Paper 1

Step 1

What does H₂O(g) represent?

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Answer

H₂O(g) represents water vapour, which may also be referred to as steam or gaseous water.

Step 2

Calculate the volume of oxygen required to react with 50 cm³ of hydrogen sulfide.

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Answer

From the balanced equation, 2 moles of H₂S react with 3 moles of O₂. Therefore, the volume of oxygen needed can be calculated using the ratio:

ext{Volume of } O₂ = rac{3}{2} imes 50 ext{ cm}^3 = 75 ext{ cm}^3

Step 3

Complete Figure 6.

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Answer

To complete Figure 6:

  1. Draw the profile line starting from the reactants, rising to a peak (representing activation energy), and then falling to a level below the starting point (indicating the exothermic nature of the reaction).
  2. Label the peak as 'Activation energy'.
  3. Indicate the difference between the starting and ending energy levels as 'Overall energy change'.

Step 4

Calculate the bond energy X for the S=O bond.

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Answer

To find bond energy X for the S=O bond, follow these calculations:

  1. Calculate the energy needed to break the bonds: extBondsbroken=4(364)+3(498)=2950extkJ/mol ext{Bonds broken} = 4(364) + 3(498) = 2950 ext{ kJ/mol}
  2. Calculate the energy released forming new bonds: extBondsformed=2950+1034=3984extkJ/mol ext{Bonds formed} = 2950 + 1034 = 3984 ext{ kJ/mol}
  3. Calculate the energy for the S=O bonds formed: 4X+4(464)=3984extkJ/mol4X + 4(464) = 3984 ext{ kJ/mol}
  4. Solve for X: 4X=39841856=2128extkJ/mol4X = 3984 - 1856 = 2128 ext{ kJ/mol}

ightarrow X = 532 ext{ kJ/mol}

Thus,bondenergyXfortheS=Obondis532kJ/mol.Thus, bond energy X for the S=O bond is 532 kJ/mol.

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