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This question is about some of the elements in group 7 of the periodic table - Edexcel - GCSE Chemistry Combined Science - Question 5 - 2021 - Paper 1

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This question is about some of the elements in group 7 of the periodic table. (a) Which row in the table correctly shows the colours and physical states of the elem... show full transcript

Worked Solution & Example Answer:This question is about some of the elements in group 7 of the periodic table - Edexcel - GCSE Chemistry Combined Science - Question 5 - 2021 - Paper 1

Step 1

Which row in the table correctly shows the colours and physical states of the elements at room temperature?

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Answer

The correct answer is D: iodine is a dark grey solid and bromine is a red-brown liquid. Other options contain at least one incorrect piece of information.

Step 2

Calculate the percentage by mass of chlorine in phosphorus oxychloride.

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Answer

First, calculate the formula mass of POCl₃:

Formula mass POCl₃=31.0+(16.0×3)+(35.5×1)=153.5\text{Formula mass POCl₃} = 31.0 + (16.0 \times 3) + (35.5 \times 1) = 153.5

Next, calculate the percentage by mass of chlorine:

%Cl=35.5153.5×100=23.1%\% \text{Cl} = \frac{35.5}{153.5} \times 100 = 23.1\%

Step 3

Show, using a calculation, which reaction, A or B, is taking place.

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Answer

To identify the correct reaction, we first calculate the number of moles of iron and the molar mass of iron chloride:

Molar mass of FeCl₃ = 55.8 + (35.5 \times 3) = 162.3 g/mol.

Number of moles of Fe = \frac{8.40}{55.8} = 0.150 moles.

From reaction A (1:1:3 stoichiometry):

  • Moles of FeCl₃ formed from 0.150 moles of Fe = 0.150 moles.
  • Mass of FeCl₃ produced = 0.150 \times 162.3 = 24.35 g.

From reaction B (2:3 stoichiometry):

  • Moles of FeCl₃ produced = 0.075 moles.
  • Mass of FeCl₃ produced = 0.075 \times 162.3 = 12.18 g.

Since 19.05g of FeCl₃ was produced, the reaction taking place is reaction A.

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