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a) Impure copper is purified by electrolysis using the apparatus shown - Edexcel - GCSE Chemistry - Question 6 - 2015 - Paper 1

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a) Impure copper is purified by electrolysis using the apparatus shown. 6 V d.c. supply impure copper electrode copper sulfate solution pure copper electrode i)... show full transcript

Worked Solution & Example Answer:a) Impure copper is purified by electrolysis using the apparatus shown - Edexcel - GCSE Chemistry - Question 6 - 2015 - Paper 1

Step 1

i) Give the name of the electrode which is made of pure copper.

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Answer

The electrode made of pure copper is known as the cathode.

Step 2

ii) Describe how each electrode will have changed at the end of the electrolysis process.

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Answer

At the anode (impure copper electrode), it will lose mass as copper ions are oxidized and enter the solution. It will become smaller as the copper atoms lose mass.

At the cathode (pure copper electrode), it will gain mass. Copper ions from the solution are reduced and deposited, forming a red-brown layer on the electrode.

Step 3

iii) Complete the sentence by putting a cross (X) in the box next to your answer.

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Answer

The correct answer is D: reduction.

Step 4

iv) Explain how copper sulfate solution conducts electricity.

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Answer

Copper sulfate solution conducts electricity due to the presence of free ions. When an electric current is applied, the copper ions (Cu²⁺) and sulfate ions (SO₄²⁻) move towards the electrodes, allowing the solution to conduct electricity.

Step 5

Explain how these products are formed from the ions in the electrolysis process, indicating how you would identify the products.

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Answer

During the electrolysis of sodium sulfate solution, the hydrogen ions (H⁺) move to the cathode where they gain electrons and form hydrogen gas:

2H++2eH22H^+ + 2e^- → H_2

At the anode, the hydroxide ions (OH⁻) lose electrons, forming oxygen gas and water:

4OH2H2O+O2+4e4OH^- → 2H_2O + O_2 + 4e^-

The hydrogen gas can be identified by its effervescence and characteristic 'popping' sound when ignited, while oxygen can be identified by relighting a glowing splint.

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