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7 (a) Qualitative tests are carried out on ionic substances to identify the ions present in the substances - Edexcel - GCSE Chemistry - Question 7 - 2019 - Paper 1

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7 (a) Qualitative tests are carried out on ionic substances to identify the ions present in the substances. (i) Explain why the test for a given ion must be unique ... show full transcript

Worked Solution & Example Answer:7 (a) Qualitative tests are carried out on ionic substances to identify the ions present in the substances - Edexcel - GCSE Chemistry - Question 7 - 2019 - Paper 1

Step 1

Explain why the test for a given ion must be unique to that ion.

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Answer

The test for a given ion must be unique to that ion to ensure accurate identification. If a test is not exclusive, it may yield false positives from other ions present, leading to misinterpretation of results. Thus, a unique test helps in confirming the presence of a specific ion without confusion or overlap with other possible substances.

Step 2

State the name of the gas produced in the test if carbonate ions are present.

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Answer

The gas produced in the test for carbonate ions when dilute hydrochloric acid is added is carbon dioxide.

Step 3

Draw one straight line from the test for each ion to the observation that shows that ion to be present.

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Answer

  1. Test for chloride ion: add dilute nitric acid followed by silver nitrate solution → white precipitate.

  2. Test for iodide ion: add dilute nitric acid followed by silver nitrate solution → yellow precipitate.

  3. Test for sulfate ion: add dilute hydrochloric acid followed by barium chloride solution → red precipitate.

Step 4

Describe tests to show the presence of each of these metal ions.

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Answer

To test for sodium ions, a flame test can be performed where a yellow flame indicates the presence of sodium. For potassium ions, a flame test will yield a lilac flame. For calcium ions, a flame test gives an orange-red flame. Lastly, aluminum can be tested by adding sodium hydroxide; if a white precipitate forms which dissolves in excess sodium hydroxide, it confirms the presence of aluminum ions.

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