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8. Ammonia can be produced from the reaction of hydrogen with nitrogen - Edexcel - GCSE Chemistry - Question 8 - 2023 - Paper 2

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8. Ammonia can be produced from the reaction of hydrogen with nitrogen. (a) What is the percentage by mass of nitrogen in ammonia, NH₃? (relative atomic masses: H ... show full transcript

Worked Solution & Example Answer:8. Ammonia can be produced from the reaction of hydrogen with nitrogen - Edexcel - GCSE Chemistry - Question 8 - 2023 - Paper 2

Step 1

What is the percentage by mass of nitrogen in ammonia, NH₃?

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Answer

To calculate the percentage by mass of nitrogen in ammonia (NH₃), we first need to find the molar mass of NH₃:

  • Molar mass of N = 14 g/mol
  • Molar mass of H = 1 g/mol

The formula for ammonia, NH₃, consists of 1 nitrogen atom and 3 hydrogen atoms. Thus,

extMolarmassofNH3=14+(3imes1)=14+3=17extg/mol ext{Molar mass of NH}_3 = 14 + (3 imes 1) = 14 + 3 = 17 ext{ g/mol}

Next, we calculate the percentage by mass of nitrogen:

extPercentagebymassofN=(mass of Nmass of NH3)×100=(1417)×10082% ext{Percentage by mass of N} = \left(\frac{\text{mass of N}}{\text{mass of NH}_3}\right) \times 100 = \left(\frac{14}{17}\right) \times 100 \approx 82\%

The correct answer is D. 82%.

Step 2

Which arrow represents the activation energy for the reaction?

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Answer

To identify the activation energy from the energy profile diagram, we look for the energy barrier that must be overcome for the reaction to proceed. In this case, arrow R represents the activation energy as it indicates the energy required to reach the transition state from the reactants.

Step 3

Explain why the boiling points of ammonia and silicon dioxide are so different.

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Answer

The difference in boiling points between ammonia (NH₃) and silicon dioxide (SiO₂) can be attributed to the types of intermolecular forces present in each substance.

  1. Intermolecular Forces in NH₃: Ammonia has hydrogen bonds due to the presence of a highly electronegative nitrogen atom bonded to hydrogen atoms. While hydrogen bonding is a strong intermolecular force, it is not as significant as the covalent network bonding present in silicon dioxide.

  2. Intermolecular Forces in SiO₂: In contrast, silicon dioxide has a giant covalent structure where each silicon atom is covalently bonded to four oxygen atoms. This network of strong covalent bonds results in a much higher boiling point.

  3. Conclusion: Therefore, the boiling point of ammonia is much lower (-33°C) because it primarily experiences hydrogen bonding, while silicon dioxide has a very high boiling point (2230°C) due to its extensive covalent network structure.

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