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1 (a) The ions in sodium chloride solution are sodium ions, Na⁺ chloride ions, Cl⁻ hydrogen ions, H⁺ hydroxide ions, OH⁻ Sodium chloride solution is electrolysed using a direct electric current - Edexcel - GCSE Chemistry - Question 1 - 2013 - Paper 1

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1 (a) The ions in sodium chloride solution are sodium ions, Na⁺ chloride ions, Cl⁻ hydrogen ions, H⁺ hydroxide ions, OH⁻ Sodium chloride solution is el... show full transcript

Worked Solution & Example Answer:1 (a) The ions in sodium chloride solution are sodium ions, Na⁺ chloride ions, Cl⁻ hydrogen ions, H⁺ hydroxide ions, OH⁻ Sodium chloride solution is electrolysed using a direct electric current - Edexcel - GCSE Chemistry - Question 1 - 2013 - Paper 1

Step 1

Which of these ions will be attracted to the cathode during the electrolysis of sodium chloride solution?

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Answer

The ions that will be attracted to the cathode during the electrolysis of sodium chloride solution are B) H⁺ and Na⁺ ions. This is because cations, or positively charged ions, migrate towards the cathode, where reduction occurs.

Step 2

Explain how the half-equation shows that chloride ions are oxidised.

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Answer

The half-equation for the production of chlorine, 2Cl⁻ → Cl₂ + 2e⁻, indicates oxidation as it illustrates the loss of electrons by chloride ions. In this process, two chloride ions each lose one electron, resulting in the formation of a chlorine molecule.

Step 3

Suggest why the solution remaining at the end of the electrolysis is alkaline.

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Answer

The solution remaining at the end of the electrolysis is alkaline because hydroxide ions (OH⁻) are produced when water is also electrolysed. This increase in hydroxide ions results in a basic (alkaline) solution.

Step 4

State what change you would make to the electrolyte to obtain metallic sodium.

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Answer

To obtain metallic sodium from the electrolysis of sodium chloride solution, I would change the electrolyte to molten sodium chloride instead of the aqueous solution. This would allow sodium ions to be reduced at the cathode to form metallic sodium.

Step 5

Explain how the oxygen is formed from ions in the solution.

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Answer

Oxygen is formed at the anode during the electrolysis of copper sulfate solution when water molecules lose electrons. The hydroxide ions (OH⁻) in the solution lose electrons, resulting in the formation of oxygen gas and water.

Step 6

Calculate the number of moles of copper, Cu, produced in this experiment.

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Answer

To calculate the number of moles of copper produced, we use the formula:

Number of moles = [ \frac{\text{mass}}{\text{molar mass}} = \frac{1.27 , ext{g}}{63.5 , \text{g/mol}} = 0.02 , \text{mol} ]

Therefore, the number of moles of copper produced is 0.02 mol.

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