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Ethane-1,2-diol can be made from ethene - Scottish Highers Chemistry - Question 9 - 2018

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Ethane-1,2-diol can be made from ethene. (a) The flow chart of an industrial process to produce ethane-1,2-diol is shown. (i) Industrial processes are designed to ... show full transcript

Worked Solution & Example Answer:Ethane-1,2-diol can be made from ethene - Scottish Highers Chemistry - Question 9 - 2018

Step 1

Using the flowchart, suggest two ways to maximise profit in this industrial process.

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Answer

  1. Recycle (waste) gases to minimize the cost and maximize the reactants' efficiency.
  2. Use a catalyst to increase the reaction rate and reduce energy requirements, thereby lowering operational costs.

Step 2

Name the process used in Separator 2 to separate ethane-1,2-diol from the larger liquid by-products.

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Answer

Fractional distillation.

Step 3

Explain fully why ethane-1,2-diol is more viscous than propan-1-ol.

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Answer

Ethane-1,2-diol has two hydroxyl (-OH) groups compared to the one hydroxyl group in propan-1-ol. The presence of more -OH groups allows for stronger hydrogen bonding between ethane-1,2-diol molecules, resulting in higher viscosity due to the increased interaction and resistance to flow.

Step 4

Draw a structural formula for a diol that contains three carbon atoms.

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Answer

The structural formula for a diol with three carbon atoms can be represented as follows:

   HO-CH2-CH(OH)-CH3

This structure shows two hydroxyl groups attached to a three-carbon backbone.

Step 5

Describe the procedure which should be used to prepare 100 cm³ of the 20% ethanol solution.

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Answer

  1. Use a pipette to measure exactly 20 cm³ of ethanol.
  2. Transfer the measured ethanol into a 100 cm³ volumetric flask.
  3. Add distilled water gradually until the total volume of the solution reaches 100 cm³. Ensure the bottom of the meniscus is at the mark for accuracy.

Step 6

Calculate the total volume, in cm³, of the 20% ethanol solution needed to treat a 3-5 kg animal.

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Answer

To treat a 3-5 kg animal with a dosage of 5 cm³ per kg, the total volume needed would be:

For 3 kg: 3 kg × 5 cm³/kg = 15 cm³

For 5 kg: 5 kg × 5 cm³/kg = 25 cm³

Thus, the total volume required is between 15 cm³ and 25 cm³.

Step 7

Draw a structural formula for another possible product of oxidation of ethane-1,2-diol.

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Answer

One possible product of oxidation is glycolic acid, represented as:

   HO-CH2-COOH

This structure features a hydroxyl group and a carboxylic acid group.

Step 8

Give a formula for sodium glycolate.

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Answer

The formula for sodium glycolate is NaC2H3O3.

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