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Essential oils from the lavender plant are used in aromatherapy - Scottish Highers Chemistry - Question 10 - 2017

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Essential oils from the lavender plant are used in aromatherapy. (a) Gas chromatography can be used to separate and identify the organic compounds in lavender oils.... show full transcript

Worked Solution & Example Answer:Essential oils from the lavender plant are used in aromatherapy - Scottish Highers Chemistry - Question 10 - 2017

Step 1

Calculate the relative concentration of linalool in lavender oil A.

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Answer

To find the relative concentration of linalool:

Using the formula:

Relative concentration=Component peak areaTotal peak area×100\text{Relative concentration} = \frac{\text{Component peak area}}{\text{Total peak area}} \times 100

Plugging in the values:

  • Linalool peak area = 31909
  • Total peak area = 79310

Relative concentration=3190979310×10040.23%\text{Relative concentration} = \frac{31909}{79310} \times 100 \approx 40.23 \%

Step 2

Identify the component found in lavender oil A that is missing from lavender oil B.

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Answer

The component that is present in lavender oil A and missing in lavender oil B is 1,8-cineole.

Step 3

Calculate the cost, in pence, of 1,8-cineole that is present in a 500 cm³ bottle of this brand of mouthwash.

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Answer

First, we calculate the total amount of 1,8-cineole in 500 cm³:

  • Concentration = 0.92 mg/cm³
  • Total volume = 500 cm³

Total mass of 1,8-cineole:

Total mass=0.92 mg/cm3×500 cm3=460 mg\text{Total mass} = 0.92 \text{ mg/cm}^3 \times 500 \text{ cm}^3 = 460 \text{ mg}

Convert mg to kg:

  • 460 mg = 0.460 g = 0.000460 kg

Now, using the cost of 1 kg of 1,8-cineole (£59.10) to find the cost of 0.000460 kg:

Cost of 1,8-cineole:

Cost=0.000460 kg×£59.10=0.0271 pounds\text{Cost} = 0.000460 \text{ kg} \times £59.10 = 0.0271 \text{ pounds}

Convert to pence:

0.0271 pounds×100=2.71 pence0.0271 \text{ pounds} \times 100 = 2.71 \text{ pence}

Step 4

Circle the chiral carbon atom in the linalool structure.

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Answer

In the provided structure of linalool, the chiral carbon is the one that is attached to four different groups. A visual identification in the structure should show the carbon atom with different substituents, which needs to be circled.

Step 5

Write the molecular formula of farnesene.

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Answer

The molecular formula of farnesene, which consists of three isoprene units, can be written as C₁₅H₂₄ or C₅H₈ depending on the structure representation.

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